Ge(H)(2‐C 6 H 4 PPh 2 ) 3 as Ligand Precursor at Ruthenium: Formation and Reactivity of [Ru(Cl){Ge(2‐C 6 H 4 PPh 2 ) 3 }

The germane [Ge(H)(2‐C 6 H 4 PPh 2 ) 3 ] ( 2 ) was synthesized by reaction of Li[Ge(2‐C 6 H 4 PPh 2 ) 3 ] ( 1 ) with water. The presence of n BuBr led to the formation of [Ge( n Bu)(2‐C 6 H 4 PPh 2 ) 3 ] ( 3 ). The complex [Ru(Cl){Ge(2‐C 6 H 4 PPh 2 ) 3 }] ( 4 ) was obtained by reaction of 2 with [R...

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Veröffentlicht in:	European journal of inorganic chemistry 2014-10, Vol.2014 (28), p.4826-4835
Hauptverfasser:	Herrmann, Roy, Braun, Thomas, Mebs, Stefan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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