New Routes to Soluble Magnesium Amidoborane Complexes

Several new synthetic routes to the known and new magnesium amidoborane complexes, [{(Nacnac)Mg(NH2BH3)}2] and [(Nacnac)Mg(NH2BH3)(THF)] (Nacnac = DipNacnac, [{N(Dip)C(Me)}2CH]–, or tBuNacnac, [{N(Dip)C(tBu)}2CH]–; Dip = C6H3iPr2‐2,6), are reported. These include the reductive dehydrogenation reacti...

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Veröffentlicht in:	European journal of inorganic chemistry 2012-05, Vol.2012 (15), p.2596-2601
Hauptverfasser:	Jones, Cameron, Bonyhady, Simon J., Nembenna, Sharanappa, Stasch, Andreas
Format:	Artikel
Sprache:	eng
Schlagworte:	Amidoborane Ammonia-borane Boranes Boron Hydrogen storage Magnesium
Online-Zugang:	Volltext
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