Electron-Rich Vaska-Type Complexes trans-[Ir(CO)Cl(2-Ph2PC6H4COOMe)2] and trans-[Ir(CO)Cl(2-Ph2PC6H4OMe)2]: Synthesis, Characterisation and Reactivity

The in‐situ‐generated dimeric precursor [Ir(CO)2Cl]2 reacts with four molar equivalents of the ligands 2‐Ph2PC6H4COOMe (a) and 2‐Ph2PC6H4OMe (b) to afford tetracoordinated complexes of the type trans‐[Ir(CO)ClL2] (1a, 1b), where L = a and b. The IR spectra of 1a and 1b in CHCl3 solution show the ter...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2011-02, Vol.2011 (6), p.835-841
Hauptverfasser:	Dutta, Dipak Kumar, Deb, Biswajit, Sarmah, Bhaskar Jyoti, Woollins, J. Derek, Slawin, Alexandra M. Z., Fuller, Amy L., Randall, Rebecca A. M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl ligands Iridium Oxidative addition Oxygen Phosphanes Vaska's complex
Online-Zugang:	Volltext
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