Heterochiral vs. Homochiral Linkage of Emissive Iridium(III) Complexes with D-Penicillaminate: Drastic Change in Emission Induced by Silver(I) Linkage

Reactions of [{Ir(ppy or ppy‐CF3)2}2(μ‐Cl)2] {Hppy = 2‐phenylpyridine, Hppy‐CF3 = 2‐[3,5‐bis(trifluoromethyl)phenyl]pyridine} with D‐penicillamine (D‐H2pen) afforded emissive IrIII mononuclear complexes [Ir(ppy or ppy‐CF3)2(D‐Hpen‐N,S)] as a 1:1 mixture of the ΔD/ΛD isomers. These complexes were con...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2010-09, Vol.2010 (25), p.3909-3913
Hauptverfasser:	Saito, Keisuke, Sarukawa, Yuta, Tsuge, Kiyoshi, Konno, Takumi
Format:	Artikel
Sprache:	eng
Schlagworte:	Chiral resolution Iridium Luminescence S ligands Substituent effects
Online-Zugang:	Volltext
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