Cyclometalated Iridium(III) Complexes as Photosensitizers for Long-Range Electron Transfer: Occurrence of a Coulomb Barrier

Six cyclometalated iridium(III) complexes were investigated to assess their potential as photosensitizers for long‐range electron transfer, and two of them were incorporated directly into covalent donor–bridge–acceptor molecules. The influence of ligand substitutions on the excited‐state properties...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2009-11, Vol.2009 (32), p.4850-4859
Hauptverfasser:	Hanss, David, Freys, Jonathan C., Bernardinelli, Gérald, Wenger, Oliver S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Donor-acceptor systems Electron transfer Iridium Photochemistry Time-resolved spectroscopy
Online-Zugang:	Volltext
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