Formation of V V Lacunary Polyoxovanadates and Interconversion Reactions of Dodecavanadate Species

Oxidation reactions of the reduced decavanadate [V IV 2 V V 8 O 26 ] 4– ( 1 ) with halide guest anions were investigated for the synthesis of V V host molecules. The reaction with Cl – afforded a new dodecavanadate, [HV V 12 O 32 (Cl)] 4– ( 3 ), which incorporated the guest chloride anion. The polyo...

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Veröffentlicht in:	European journal of inorganic chemistry 2009-12, Vol.2009 (34), p.5156-5163
Hauptverfasser:	Okaya, Kenji, Kobayashi, Tetsuhiro, Koyama, Yuki, Hayashi, Yoshihito, Isobe, Kiyoshi
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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