Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds
Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisati...
Gespeichert in:
| Veröffentlicht in: | European Journal of Inorganic Chemistry 2009-10, Vol.2009 (29-30), p.4483-4490 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4490 |
|---|---|
| container_issue | 29-30 |
| container_start_page | 4483 |
| container_title | European Journal of Inorganic Chemistry |
| container_volume | 2009 |
| creator | Matuska, Vit Tersago, Karla Kilian, Petr Van Alsenoy, Christian Blockhuys, Frank Slawin, Alexandra M. Z. Woollins, J. Derek |
| description | Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Metallasulfur–nitrogen chemistry continues to surprise theoreticians and synthetic chemists. During the synthesis of a simple MS2N2 complex we obtained a binuclear complex. |
| doi_str_mv | 10.1002/ejic.200900541 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_ejic_200900541</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>EJIC200900541</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3481-d59e5d6423f39745a66857797504b70d4e596a7107ab4951b004971ce62077bd3</originalsourceid><addsrcrecordid>eNqF0L9PwkAUwPGL0UREV-cbIaH4rverNziYBisEMAHUxOVyba8RLJbctVH-e0EMcXN6b3ifN3wRuibQJwDhjV0ts34IoAA4IyeoRUCpAEQUnu52RllAFIvO0YX3KwCgQEULLSZVabOmNA6bjxzHbutrU-J57Zqsbpz1uCpwvJl05uE07OLOBN_iuOrh2VsPD133B81saWq7w9V6UzUfub9EZ4Upvb36nW30dD9YxA_B-DEZxnfjIKMsIkHOleW5YCEtqJKMGyEiLqWSHFgqIWeWK2EkAWlSpjhJAZiSJLMiBCnTnLZR__A3c5X3zhZ645Zr47aagN430fsm-thkB9QBfC5Lu_3nWg9Gw_ivDQ526Wv7dbTGvWshqeT6ZZro6Fklo-RV6Yh-A4RpcII</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds</title><source>Wiley-Blackwell Full Collection</source><creator>Matuska, Vit ; Tersago, Karla ; Kilian, Petr ; Van Alsenoy, Christian ; Blockhuys, Frank ; Slawin, Alexandra M. Z. ; Woollins, J. Derek</creator><creatorcontrib>Matuska, Vit ; Tersago, Karla ; Kilian, Petr ; Van Alsenoy, Christian ; Blockhuys, Frank ; Slawin, Alexandra M. Z. ; Woollins, J. Derek</creatorcontrib><description>Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Metallasulfur–nitrogen chemistry continues to surprise theoreticians and synthetic chemists. During the synthesis of a simple MS2N2 complex we obtained a binuclear complex.</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.200900541</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Density functional calculations ; Metallacycles ; Rhodium ; Structure elucidation</subject><ispartof>European Journal of Inorganic Chemistry, 2009-10, Vol.2009 (29-30), p.4483-4490</ispartof><rights>Copyright © 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3481-d59e5d6423f39745a66857797504b70d4e596a7107ab4951b004971ce62077bd3</citedby><cites>FETCH-LOGICAL-c3481-d59e5d6423f39745a66857797504b70d4e596a7107ab4951b004971ce62077bd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fejic.200900541$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fejic.200900541$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>313,314,776,780,788,1411,27899,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Matuska, Vit</creatorcontrib><creatorcontrib>Tersago, Karla</creatorcontrib><creatorcontrib>Kilian, Petr</creatorcontrib><creatorcontrib>Van Alsenoy, Christian</creatorcontrib><creatorcontrib>Blockhuys, Frank</creatorcontrib><creatorcontrib>Slawin, Alexandra M. Z.</creatorcontrib><creatorcontrib>Woollins, J. Derek</creatorcontrib><title>Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds</title><title>European Journal of Inorganic Chemistry</title><addtitle>Eur. J. Inorg. Chem</addtitle><description>Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Metallasulfur–nitrogen chemistry continues to surprise theoreticians and synthetic chemists. During the synthesis of a simple MS2N2 complex we obtained a binuclear complex.</description><subject>Density functional calculations</subject><subject>Metallacycles</subject><subject>Rhodium</subject><subject>Structure elucidation</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqF0L9PwkAUwPGL0UREV-cbIaH4rverNziYBisEMAHUxOVyba8RLJbctVH-e0EMcXN6b3ifN3wRuibQJwDhjV0ts34IoAA4IyeoRUCpAEQUnu52RllAFIvO0YX3KwCgQEULLSZVabOmNA6bjxzHbutrU-J57Zqsbpz1uCpwvJl05uE07OLOBN_iuOrh2VsPD133B81saWq7w9V6UzUfub9EZ4Upvb36nW30dD9YxA_B-DEZxnfjIKMsIkHOleW5YCEtqJKMGyEiLqWSHFgqIWeWK2EkAWlSpjhJAZiSJLMiBCnTnLZR__A3c5X3zhZ645Zr47aagN430fsm-thkB9QBfC5Lu_3nWg9Gw_ivDQ526Wv7dbTGvWshqeT6ZZro6Fklo-RV6Yh-A4RpcII</recordid><startdate>200910</startdate><enddate>200910</enddate><creator>Matuska, Vit</creator><creator>Tersago, Karla</creator><creator>Kilian, Petr</creator><creator>Van Alsenoy, Christian</creator><creator>Blockhuys, Frank</creator><creator>Slawin, Alexandra M. Z.</creator><creator>Woollins, J. Derek</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200910</creationdate><title>Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds</title><author>Matuska, Vit ; Tersago, Karla ; Kilian, Petr ; Van Alsenoy, Christian ; Blockhuys, Frank ; Slawin, Alexandra M. Z. ; Woollins, J. Derek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3481-d59e5d6423f39745a66857797504b70d4e596a7107ab4951b004971ce62077bd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Density functional calculations</topic><topic>Metallacycles</topic><topic>Rhodium</topic><topic>Structure elucidation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matuska, Vit</creatorcontrib><creatorcontrib>Tersago, Karla</creatorcontrib><creatorcontrib>Kilian, Petr</creatorcontrib><creatorcontrib>Van Alsenoy, Christian</creatorcontrib><creatorcontrib>Blockhuys, Frank</creatorcontrib><creatorcontrib>Slawin, Alexandra M. Z.</creatorcontrib><creatorcontrib>Woollins, J. Derek</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European Journal of Inorganic Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matuska, Vit</au><au>Tersago, Karla</au><au>Kilian, Petr</au><au>Van Alsenoy, Christian</au><au>Blockhuys, Frank</au><au>Slawin, Alexandra M. Z.</au><au>Woollins, J. Derek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds</atitle><jtitle>European Journal of Inorganic Chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2009-10</date><risdate>2009</risdate><volume>2009</volume><issue>29-30</issue><spage>4483</spage><epage>4490</epage><pages>4483-4490</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>Cp*Rh(S2N2) was prepared as a microcrystalline solid by using [S4N3]Cl in liquid ammonia or [nBu2Sn(S2N2)]2. It was characterised by NMR, IR and Raman spectroscopy andmass spectrometry. Low‐temperature crystal structures of Cp*Co(S2N2) and Cp*Ir(S2N2) were determined. The experimental characterisation of the Cp*M(S2N2) complexes was complemented by calculated geometries and bond orders at the DFT/B1B95 level of theory. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
Metallasulfur–nitrogen chemistry continues to surprise theoreticians and synthetic chemists. During the synthesis of a simple MS2N2 complex we obtained a binuclear complex.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.200900541</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1434-1948 |
| ispartof | European Journal of Inorganic Chemistry, 2009-10, Vol.2009 (29-30), p.4483-4490 |
| issn | 1434-1948 1099-0682 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_ejic_200900541 |
| source | Wiley-Blackwell Full Collection |
| subjects | Density functional calculations Metallacycles Rhodium Structure elucidation |
| title | Molecular and Crystal Structures of CpM(S2N2) (M = Co, Rh, Ir) and Related Compounds |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-11T20%3A37%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Molecular%20and%20Crystal%20Structures%20of%20CpM(S2N2)%20(M%20=%20Co,%20Rh,%20Ir)%20and%20Related%20Compounds&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.au=Matuska,%20Vit&rft.date=2009-10&rft.volume=2009&rft.issue=29-30&rft.spage=4483&rft.epage=4490&rft.pages=4483-4490&rft.issn=1434-1948&rft.eissn=1099-0682&rft_id=info:doi/10.1002/ejic.200900541&rft_dat=%3Cwiley_cross%3EEJIC200900541%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |