P-Chirogenic Benzo-Fused Phenoxaphosphane: Synthesis, Resolution and Study of the Stereochemical Properties of the Corresponding Palladium Complexes

The synthesis and resolution of chiral phenoxaphosphane 3, with the stereogenic center at the phosphorus atom, is described. Compound 3 has been synthesized following a well‐known procedure for trapping a phosphorus atom within a six‐membered ring. The resolution of the racemic mixture of 3 was achi...

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Veröffentlicht in:European Journal of Inorganic Chemistry 2008-03, Vol.2008 (8), p.1309-1317
Hauptverfasser: Doro, Franco, Lutz, Martin, Reek, Joost N. H., Spek, Anthony L., van Leeuwen, Piet W. N. M.
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Sprache:eng
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