Surface-Assisted Synthesis and Behavior of Dimetallic Mixed-Metal Complexes [M2Cl2(μ-Cl)4(CO)6M′(L)2] (M = Ru, Os; M′ = Fe, Co; L = CH3CH2OH, H2O)

The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds. A linear, dim...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2007-08, Vol.2007 (22), p.3497-3508
Hauptverfasser:	Jakonen, Minna, Hirva, Pipsa, Nivajärvi, Taina, Kallinen, Mirja, Haukka, Matti
Format:	Artikel
Sprache:	eng
Schlagworte:	Cobalt Iron Osmium Ruthenium Synthesis design
Online-Zugang:	Volltext
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