New Aspects for Modeling Supramolecular Interactions in Vanadium Haloperoxidases: β-Cyclodextrin Inclusion Compounds of cis-Dioxovanadium(V) Complexes
The reaction of potassium vanadate and the hydrazone ligand derived from Schiff base condensation of salicylaldehyde and biphenyl‐4‐carboxylic acid hydrazide (H2salhybiph) in the presence of β‐cyclodextrin (β‐CD) in water yields the 1:1 inclusion compound K[VO2(salhybiph)@ β‐CD]. The characterizatio...
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Veröffentlicht in: | European Journal of Inorganic Chemistry 2007-04, Vol.2007 (11), p.1487-1491 |
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creator | Lippold, Ines Görls, Helmar Plass, Winfried |
description | The reaction of potassium vanadate and the hydrazone ligand derived from Schiff base condensation of salicylaldehyde and biphenyl‐4‐carboxylic acid hydrazide (H2salhybiph) in the presence of β‐cyclodextrin (β‐CD) in water yields the 1:1 inclusion compound K[VO2(salhybiph)@ β‐CD]. The characterization in solution confirmed the integrity of the inclusion compound in different polar solvents such as DMSO and water. The inclusion compound crystallizes with additional water molecules in the triclinic space group P1. The supramolecular aggregation of the inclusion compound in the solid state is established through hydrogen bonding interactions between adjacent β‐CD hosts and the π–π stacking ability of the ligand side chain of the guest complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007) |
doi_str_mv | 10.1002/ejic.200601225 |
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The characterization in solution confirmed the integrity of the inclusion compound in different polar solvents such as DMSO and water. The inclusion compound crystallizes with additional water molecules in the triclinic space group P1. The supramolecular aggregation of the inclusion compound in the solid state is established through hydrogen bonding interactions between adjacent β‐CD hosts and the π–π stacking ability of the ligand side chain of the guest complexes. (© Wiley‐VCH Verlag GmbH & Co. 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J. Inorg. Chem</addtitle><description>The reaction of potassium vanadate and the hydrazone ligand derived from Schiff base condensation of salicylaldehyde and biphenyl‐4‐carboxylic acid hydrazide (H2salhybiph) in the presence of β‐cyclodextrin (β‐CD) in water yields the 1:1 inclusion compound K[VO2(salhybiph)@ β‐CD]. The characterization in solution confirmed the integrity of the inclusion compound in different polar solvents such as DMSO and water. The inclusion compound crystallizes with additional water molecules in the triclinic space group P1. The supramolecular aggregation of the inclusion compound in the solid state is established through hydrogen bonding interactions between adjacent β‐CD hosts and the π–π stacking ability of the ligand side chain of the guest complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</description><subject>Cyclodextrins</subject><subject>Host-guest systems</subject><subject>Inclusion compounds</subject><subject>Vanadium</subject><subject>X-ray diffraction</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><recordid>eNqFkE1u2zAQRoWiBZKm2WbNZbuQMyRFyerOUGzHQZwump8lQVGjgi4tCqTUyCfpPXKQnqlyHATZBRhgZoDvvcUXRWcUJhSAnePG6AkDSIEyJj5ExxTyPIZ0yj6Od8KTmObJ9Cj6HMIGADjw9Dj6e4OPZBZa1F0gtfNk7Sq0pvlFfvatV1tnUfdWebJqOvRKd8Y1gZiG3KtGVabfkktlXYveDaZSAcN38u8pLnbajp6h82Ny1Wjbh5Ejhdu2rm-qQFxNtAnxhXGD-_Ni-nr_7TlhccDwJfpUKxvw9GWfRHeL-W1xGV__WK6K2XWsOctEnFVMlNOsplXKS6o0TRMOdFpyxmomqE74_gWWlgKpqDlCCQkmFRWMIh_nJJocvNq7EDzWsvVmq_xOUpD7WuW-Vvla6wjkB-DRWNy9k5bzq1Xxlo0PrAkdDq-s8r9lmvFMyIebpRT5erHmF0uZ8_-8l451</recordid><startdate>200704</startdate><enddate>200704</enddate><creator>Lippold, Ines</creator><creator>Görls, Helmar</creator><creator>Plass, Winfried</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200704</creationdate><title>New Aspects for Modeling Supramolecular Interactions in Vanadium Haloperoxidases: β-Cyclodextrin Inclusion Compounds of cis-Dioxovanadium(V) Complexes</title><author>Lippold, Ines ; Görls, Helmar ; Plass, Winfried</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3275-7d25b87f1d63b1ac1643018b322f251c433018026b5e15f3e0b04e4d1521e31e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><topic>Cyclodextrins</topic><topic>Host-guest systems</topic><topic>Inclusion compounds</topic><topic>Vanadium</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lippold, Ines</creatorcontrib><creatorcontrib>Görls, Helmar</creatorcontrib><creatorcontrib>Plass, Winfried</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>European Journal of Inorganic Chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lippold, Ines</au><au>Görls, Helmar</au><au>Plass, Winfried</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Aspects for Modeling Supramolecular Interactions in Vanadium Haloperoxidases: β-Cyclodextrin Inclusion Compounds of cis-Dioxovanadium(V) Complexes</atitle><jtitle>European Journal of Inorganic Chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2007-04</date><risdate>2007</risdate><volume>2007</volume><issue>11</issue><spage>1487</spage><epage>1491</epage><pages>1487-1491</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The reaction of potassium vanadate and the hydrazone ligand derived from Schiff base condensation of salicylaldehyde and biphenyl‐4‐carboxylic acid hydrazide (H2salhybiph) in the presence of β‐cyclodextrin (β‐CD) in water yields the 1:1 inclusion compound K[VO2(salhybiph)@ β‐CD]. The characterization in solution confirmed the integrity of the inclusion compound in different polar solvents such as DMSO and water. The inclusion compound crystallizes with additional water molecules in the triclinic space group P1. The supramolecular aggregation of the inclusion compound in the solid state is established through hydrogen bonding interactions between adjacent β‐CD hosts and the π–π stacking ability of the ligand side chain of the guest complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.200601225</doi><tpages>5</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Cyclodextrins Host-guest systems Inclusion compounds Vanadium X-ray diffraction |
title | New Aspects for Modeling Supramolecular Interactions in Vanadium Haloperoxidases: β-Cyclodextrin Inclusion Compounds of cis-Dioxovanadium(V) Complexes |
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