A New Silver(I) Aggregate Having an Octagonal Ag 4 S 4 Core Where μ 3 ‐S Bonding Interactions Lead to a Nanotube Assembly that Exhibits Quasiaromaticity

Silver(I) chloride reacts with 2‐mercapto‐3,4,5,6‐tetrahydropyrimidine (StpmH 2 , C 4 H 8 N 2 S) in DMSO with excess triethylamine to give a complex of formula {[Ag 4 Cl 4 (μ 3 ‐StpmH 2 ) 4 ] n } ( 1 ). The product was characterized by elemental analyses, FTIR far‐IR, UV/Vis, and 1 H and 109 Ag NMR...

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Veröffentlicht in:	European journal of inorganic chemistry 2007-03, Vol.2007 (9), p.1219-1224
Hauptverfasser:	Zartilas, Sotiris, Kourkoumelis, Nikolaos, Hadjikakou, Sotiris K., Hadjiliadis, Nick, Zachariadis, Panagiotis, Kubicki, Maciej, Denisov, Alexey Yu, Butler, Ian S.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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