Nickel-Organic Coordination Layers with Different Directional Cavities
The two new metal‐organic coordination frameworks [Ni2(pydc)2(4,4′‐bpy)(H2O)4]n·0.5n(4,4′‐bpy)2H2O (1) and [Ni2(pydc)2(2,2′‐bpy)2(H2O)2]n·2nH2O (2) (H2pydc = pyridine‐3,4‐dicarboxylic acid; bpy = bipyridine) have been synthesised under hydrothermal conditions and characterised by single‐crystal X‐ra...
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| Veröffentlicht in: | European Journal of Inorganic Chemistry 2006, Vol.2006 (23), p.4852-4856 |
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| container_end_page | 4856 |
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| container_issue | 23 |
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| container_title | European Journal of Inorganic Chemistry |
| container_volume | 2006 |
| creator | Zhou, Youfu Yue, Chengyang Yuan, Daqiang Chen, Lian Chen, Jiutong Lan, Anjian Jiang, Feilong Hong, Maochun |
| description | The two new metal‐organic coordination frameworks [Ni2(pydc)2(4,4′‐bpy)(H2O)4]n·0.5n(4,4′‐bpy)2H2O (1) and [Ni2(pydc)2(2,2′‐bpy)2(H2O)2]n·2nH2O (2) (H2pydc = pyridine‐3,4‐dicarboxylic acid; bpy = bipyridine) have been synthesised under hydrothermal conditions and characterised by single‐crystal X‐ray diffraction analysis. The structure of 1 contains parallel rectangular channels that accommodate large 4,4′‐bpy guests while that of 2 contains vertical channels coordinated to 2,2′‐bpy ligands. Their magnetic analyses show that they exhibit different magnetic interactions. The red shifts of the peak in their emission spectra relative to those of the the free ligands could be attributable to the metal–ligand coordination. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006) |
| doi_str_mv | 10.1002/ejic.200600539 |
| format | Review |
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The structure of 1 contains parallel rectangular channels that accommodate large 4,4′‐bpy guests while that of 2 contains vertical channels coordinated to 2,2′‐bpy ligands. Their magnetic analyses show that they exhibit different magnetic interactions. The red shifts of the peak in their emission spectra relative to those of the the free ligands could be attributable to the metal–ligand coordination. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.200600539</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Carboxylate ligands ; Coordination polymers ; Luminescence ; Magnetic properties ; Nickel</subject><ispartof>European Journal of Inorganic Chemistry, 2006, Vol.2006 (23), p.4852-4856</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH & Co. 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KGaA, 69451 Weinheim, Germany, 2006)</description><subject>Carboxylate ligands</subject><subject>Coordination polymers</subject><subject>Luminescence</subject><subject>Magnetic properties</subject><subject>Nickel</subject><issn>1434-1948</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>review</rsrctype><creationdate>2006</creationdate><recordtype>review</recordtype><recordid>eNqFkE1PAjEURRujiYhuXc8fGHx9_Zh2aQZQzARcaHTXlNLRwsiYdiLy74VgiDtX7ybvnrs4hFxTGFAAvPHL4AYIIAEE0yekR0HrHKTC013mjOdUc3VOLlJaAgADJntkPA1u5Zt8Ft_sOrisbNu4CGvbhXadVXbrY8o2oXvPhqGuffTrbpeid_u_bbLSfoUu-HRJzmrbJH_1e_vkeTx6Ku_zanY3KW-r3CFHnaPVnCv0hVYgnGLOSUfRYq3nnLt5zWixUMoxrwRHaQVTC8Q5UgFSeBSO9cngsOtim1L0tfmM4cPGraFg9hbM3oI5WtgB-gBsQuO3_7TN6GFS_mXzAxtS57-PrI0rIwtWCPMyvTOvFcrhI6uMYD_Cfm-j</recordid><startdate>200612</startdate><enddate>200612</enddate><creator>Zhou, Youfu</creator><creator>Yue, Chengyang</creator><creator>Yuan, Daqiang</creator><creator>Chen, Lian</creator><creator>Chen, Jiutong</creator><creator>Lan, Anjian</creator><creator>Jiang, Feilong</creator><creator>Hong, Maochun</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200612</creationdate><title>Nickel-Organic Coordination Layers with Different Directional Cavities</title><author>Zhou, Youfu ; Yue, Chengyang ; Yuan, Daqiang ; Chen, Lian ; Chen, Jiutong ; Lan, Anjian ; Jiang, Feilong ; Hong, Maochun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2429-2a94482e79805c83cc6c12a2f9b44cbf317d88c3e85426a538d22b215065e25c3</frbrgroupid><rsrctype>reviews</rsrctype><prefilter>reviews</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Carboxylate ligands</topic><topic>Coordination polymers</topic><topic>Luminescence</topic><topic>Magnetic properties</topic><topic>Nickel</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Youfu</creatorcontrib><creatorcontrib>Yue, Chengyang</creatorcontrib><creatorcontrib>Yuan, Daqiang</creatorcontrib><creatorcontrib>Chen, Lian</creatorcontrib><creatorcontrib>Chen, Jiutong</creatorcontrib><creatorcontrib>Lan, Anjian</creatorcontrib><creatorcontrib>Jiang, Feilong</creatorcontrib><creatorcontrib>Hong, Maochun</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Youfu</au><au>Yue, Chengyang</au><au>Yuan, Daqiang</au><au>Chen, Lian</au><au>Chen, Jiutong</au><au>Lan, Anjian</au><au>Jiang, Feilong</au><au>Hong, Maochun</au><format>journal</format><genre>article</genre><ristype>GEN</ristype><atitle>Nickel-Organic Coordination Layers with Different Directional Cavities</atitle><jtitle>European Journal of Inorganic Chemistry</jtitle><addtitle>Eur. J. Inorg. Chem</addtitle><date>2006-12</date><risdate>2006</risdate><volume>2006</volume><issue>23</issue><spage>4852</spage><epage>4856</epage><pages>4852-4856</pages><issn>1434-1948</issn><eissn>1099-0682</eissn><abstract>The two new metal‐organic coordination frameworks [Ni2(pydc)2(4,4′‐bpy)(H2O)4]n·0.5n(4,4′‐bpy)2H2O (1) and [Ni2(pydc)2(2,2′‐bpy)2(H2O)2]n·2nH2O (2) (H2pydc = pyridine‐3,4‐dicarboxylic acid; bpy = bipyridine) have been synthesised under hydrothermal conditions and characterised by single‐crystal X‐ray diffraction analysis. The structure of 1 contains parallel rectangular channels that accommodate large 4,4′‐bpy guests while that of 2 contains vertical channels coordinated to 2,2′‐bpy ligands. Their magnetic analyses show that they exhibit different magnetic interactions. The red shifts of the peak in their emission spectra relative to those of the the free ligands could be attributable to the metal–ligand coordination. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/ejic.200600539</doi><tpages>5</tpages></addata></record> |
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| subjects | Carboxylate ligands Coordination polymers Luminescence Magnetic properties Nickel |
| title | Nickel-Organic Coordination Layers with Different Directional Cavities |
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