Formation of Triple-Stranded Dinuclear Helicates with Dicatecholimine Ligands: The Influence of Steric Hindrance at the Spacer

A series of new imine‐bridged dicatechol ligands 3a–f‐H4 with sterically demanding groups at the spacers are used for the formation of titanium(IV) complexes M4[(3)3Ti2]. All three ligands 3a–c‐H4 form triple‐stranded dinuclear helicates. When the bulky ligands 3a‐H4 or 3c‐H4 are used with potassium...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2006-01, Vol.2006 (1), p.244-251
Hauptverfasser:	Janser, Ingo, Albrecht, Markus, Hunger, Katharina, Burk, Simon, Rissanen, Kari
Format:	Artikel
Sprache:	eng
Schlagworte:	Bulky ligands Dinuclear complexes Helicates Meso-helicates Self-assembly Titanium
Online-Zugang:	Volltext
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