Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions
The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first‐row transition metal salts in the presence of 2‐aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C5N2H7)4Mo8O26 (1), zero‐dimensional (C5N2H7)6Mo7O24·3...
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| Veröffentlicht in: | European Journal of Inorganic Chemistry 2005-08, Vol.2005 (15), p.3080-3087 |
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| container_end_page | 3087 |
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| container_issue | 15 |
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| container_title | European Journal of Inorganic Chemistry |
| container_volume | 2005 |
| creator | Pavani, Katikaneani Ramanan, Arunachalam |
| description | The hydrothermal reaction of an aqueous ammonium heptamolybdate solution with first‐row transition metal salts in the presence of 2‐aminopyridine at around 180 °C and under autogenous pressure yields several molybdates, such as the 1D chains in (C5N2H7)4Mo8O26 (1), zero‐dimensional (C5N2H7)6Mo7O24·3H2O (2), and the first synthesis of Lindgrenite [Cu3Mo2O8(OH)2 (3)] The structures of these materials were established by single‐crystal and powder X‐ray diffraction techniques. The crystal structures of wolframite‐based MnMoO4 (4) and ZnMoO4 (5) were established by powder X‐ray diffraction. The role of 2‐aminopyridine (2‐ampy) in the formation of the different solids under hydrothermal conditions is discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005) |
| doi_str_mv | 10.1002/ejic.200500092 |
| format | Article |
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The crystal structures of wolframite‐based MnMoO4 (4) and ZnMoO4 (5) were established by powder X‐ray diffraction. The role of 2‐aminopyridine (2‐ampy) in the formation of the different solids under hydrothermal conditions is discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)</description><identifier>ISSN: 1434-1948</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/ejic.200500092</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Crystal structure ; Hydrothermal synthesis ; Molybdenum ; N ligands</subject><ispartof>European Journal of Inorganic Chemistry, 2005-08, Vol.2005 (15), p.3080-3087</ispartof><rights>Copyright © 2005 WILEY‐VCH Verlag GmbH & Co. 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| issn | 1434-1948 1099-0682 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Crystal structure Hydrothermal synthesis Molybdenum N ligands |
| title | Influence of 2-Aminopyridine on the Formation of Molybdates under Hydrothermal Conditions |
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