Exploring the Reactivity towards Acidic Protic Ligands of the Di-μ-hydroxo Complex [NBu4]2[Pd2{C4(COOMe)4}2(μ-OH)2]: A Convenient Precursor in the Preparation of New Palladacyclopentadiene Complexes

The dinuclear hydroxo complex [NBu4]2[Pd2{C4(COOMe)4}2(μ‐OH)2] (I) reacts in a 1:2 molar ratio with a wide variety of protic electrophiles H(L) bearing different sets of donor atoms (L = OO, NS or ON) to give the mononuclear anionic palladium(II) derivatives with the general formula [Pd{C4(COOMe)4}(...

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Veröffentlicht in:	European Journal of Inorganic Chemistry 2005, Vol.2005 (12), p.2360-2367
Hauptverfasser:	Sánchez, Gregorio, Vives, Jorge, López, Gregorio, Serrano, José Luis, García, Luis, Pérez, José
Format:	Review
Sprache:	eng
Schlagworte:	Cycloaddition Hydroxo complexes Metallacycles Palladacyclopentadiene complexes
Online-Zugang:	Volltext
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