Nonbridging and Monodentate Carboxylate Coordination of Calcium(2+) Through the Use of Intramolecular Hydrogen Bonding in a New Sterically Hindered Carboxylate Ligand

The sterically hindered carboxylate ligand 2,6‐bis(2,2‐dimethylpropionylamino)benzoic acid (HL) has been prepared. The two intramolecular hydrogen bonds in HL are exploited to restrict the corresponding carboxylate anion (L−) to nonbridging coordination and to preorganise its sterically bulky substi...

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Veröffentlicht in:	European journal of inorganic chemistry 2004-11, Vol.2004 (21), p.4237-4241
Hauptverfasser:	Crane, Jonathan D., Moreton, David J., Rogerson, Eleanor
Format:	Artikel
Sprache:	eng
Schlagworte:	Calcium Carboxylate ligands Hydrogen bonds Sterically hindered ligands
Online-Zugang:	Volltext
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