Dynamic Behavior of an N-Metalated β-Enaminoimine Complex − Preparation of N-Phosphanylenamine and β-Enaminoimine Derivatives

Variable‐temperature NMR spectroscopy of the β‐enaminoimine complex 2 showed a dynamic process which was attributed to an internal fluxional aldimido N‐zirconated π‐linear/σ‐bent structure. Such an internal rearrangement has been previously proposed to occur in these systems but never observed. We h...

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Veröffentlicht in:	European journal of inorganic chemistry 2003-03, Vol.2003 (5), p.960-968
Hauptverfasser:	Maraval, Alexandrine, Owsianik, Krzysztof, Arquier, Damien, Igau, Alain, Coppel, Yannick, Donnadieu, Bruno, Zablocka, Maria, Majoral, Jean-Pierre
Format:	Artikel
Sprache:	eng
Schlagworte:	Imines Metallocenes N ligands NMR spectroscopy Transmetalation Zirconium
Online-Zugang:	Volltext
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