The Structural Role of the Triflate Anion in the Non-Covalent Silver Polymer [Ag(LOH)2(CF3SO3)(CH3CN)] {LOH = α-(4-Pyridyl)benzhydrol}

Ag(CF3SO3) was reacted with the ligand α‐(4‐pyridyl)benzhydrol (LOH) in order to build a mixed organic/inorganic analogue of wheel‐and‐axle diols. In the resulting [Ag(LOH)2(CF3SO3)(CH3CN)] complex, the metal is four‐coordinate, with two pyridines trans each other and a triflate and an acetonitrile...

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Veröffentlicht in:	European journal of inorganic chemistry 2004-05, Vol.2004 (10), p.1985-1991
Hauptverfasser:	Bacchi, Alessia, Bosetti, Elsa, Carcelli, Mauro, Pelagatti, Paolo, Rogolino, Dominga
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystal engineering Hydrogen bonds Molecular tectonics Non-covalent interactions Silver compounds
Online-Zugang:	Volltext
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