Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels
Photocatalytic CO reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO in the conver...
Gespeichert in:
| Veröffentlicht in: | ChemSusChem 2017-12, Vol.10 (23), p.4709-4714 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 4714 |
|---|---|
| container_issue | 23 |
| container_start_page | 4709 |
| container_title | ChemSusChem |
| container_volume | 10 |
| creator | Zhang, Li Kong, Guoguo Meng, Yaping Tian, Jinshu Zhang, Lijie Wan, Shaolong Lin, Jingdong Wang, Yong |
| description | Photocatalytic CO
reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO
in the conversion of CO
-H
O into fuels. Specifically, it was found that direct coupling of thermo- and photocatalysis over Au-Ru/TiO
leads to activity 15 times higher (T=358 K; ca. 99 % CH
selectivity) in the conversion of CO
-H
O into fuels than that of photocatalytic water splitting. This is ascribed to the promoting effect of thermocatalytic hydrogenation of CO
by hydrogen atoms generated in situ by photocatalytic water splitting. |
| doi_str_mv | 10.1002/cssc.201701472 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_cssc_201701472</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>29045065</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1075-1a98b1602c618c62b15bbd5c84d649bd9e0ff70d6209ba85402682b2bc34ee083</originalsourceid><addsrcrecordid>eNo9kLFOwzAURS0EoqWwMiL_QMKzYzvOiAKlSJXCUBBbZDsODUriyk6Q-vdNVejy7hvOvcNB6J5ATADoownBxBRICoSl9ALNiRQs4oJ9XZ7_hMzQTQg_AAIyIa7RjGbAOAg-R5_PjbdmwLkbd23Tf2NX483W-s5FWPUVft-6wRk1qHYfmoBr5ye0_7U-NK4_wnmBKY5W0ylw0w8OL0fbhlt0Vas22Lu_XKCP5csmX0Xr4vUtf1pHhkDKI6IyqYkAagSRRlBNuNYVN5JVgmW6yizUdQqVoJBpJTkDKiTVVJuEWQsyWaD4tGu8C8Hbutz5plN-XxIoj4LKo6DyLGgqPJwKu1F3tjrj_0aSA_vaX4I</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels</title><source>MEDLINE</source><source>Access via Wiley Online Library</source><creator>Zhang, Li ; Kong, Guoguo ; Meng, Yaping ; Tian, Jinshu ; Zhang, Lijie ; Wan, Shaolong ; Lin, Jingdong ; Wang, Yong</creator><creatorcontrib>Zhang, Li ; Kong, Guoguo ; Meng, Yaping ; Tian, Jinshu ; Zhang, Lijie ; Wan, Shaolong ; Lin, Jingdong ; Wang, Yong</creatorcontrib><description>Photocatalytic CO
reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO
in the conversion of CO
-H
O into fuels. Specifically, it was found that direct coupling of thermo- and photocatalysis over Au-Ru/TiO
leads to activity 15 times higher (T=358 K; ca. 99 % CH
selectivity) in the conversion of CO
-H
O into fuels than that of photocatalytic water splitting. This is ascribed to the promoting effect of thermocatalytic hydrogenation of CO
by hydrogen atoms generated in situ by photocatalytic water splitting.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201701472</identifier><identifier>PMID: 29045065</identifier><language>eng</language><publisher>Germany</publisher><subject>Carbon Dioxide - chemistry ; Catalysis ; Hot Temperature ; Hydrogen - chemistry ; Hydrogenation ; Photochemical Processes ; Photolysis ; Solar Energy ; Water</subject><ispartof>ChemSusChem, 2017-12, Vol.10 (23), p.4709-4714</ispartof><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1075-1a98b1602c618c62b15bbd5c84d649bd9e0ff70d6209ba85402682b2bc34ee083</citedby><cites>FETCH-LOGICAL-c1075-1a98b1602c618c62b15bbd5c84d649bd9e0ff70d6209ba85402682b2bc34ee083</cites><orcidid>0000-0003-0686-6908 ; 0000-0002-8460-7410</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29045065$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Li</creatorcontrib><creatorcontrib>Kong, Guoguo</creatorcontrib><creatorcontrib>Meng, Yaping</creatorcontrib><creatorcontrib>Tian, Jinshu</creatorcontrib><creatorcontrib>Zhang, Lijie</creatorcontrib><creatorcontrib>Wan, Shaolong</creatorcontrib><creatorcontrib>Lin, Jingdong</creatorcontrib><creatorcontrib>Wang, Yong</creatorcontrib><title>Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>Photocatalytic CO
reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO
in the conversion of CO
-H
O into fuels. Specifically, it was found that direct coupling of thermo- and photocatalysis over Au-Ru/TiO
leads to activity 15 times higher (T=358 K; ca. 99 % CH
selectivity) in the conversion of CO
-H
O into fuels than that of photocatalytic water splitting. This is ascribed to the promoting effect of thermocatalytic hydrogenation of CO
by hydrogen atoms generated in situ by photocatalytic water splitting.</description><subject>Carbon Dioxide - chemistry</subject><subject>Catalysis</subject><subject>Hot Temperature</subject><subject>Hydrogen - chemistry</subject><subject>Hydrogenation</subject><subject>Photochemical Processes</subject><subject>Photolysis</subject><subject>Solar Energy</subject><subject>Water</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kLFOwzAURS0EoqWwMiL_QMKzYzvOiAKlSJXCUBBbZDsODUriyk6Q-vdNVejy7hvOvcNB6J5ATADoownBxBRICoSl9ALNiRQs4oJ9XZ7_hMzQTQg_AAIyIa7RjGbAOAg-R5_PjbdmwLkbd23Tf2NX483W-s5FWPUVft-6wRk1qHYfmoBr5ye0_7U-NK4_wnmBKY5W0ylw0w8OL0fbhlt0Vas22Lu_XKCP5csmX0Xr4vUtf1pHhkDKI6IyqYkAagSRRlBNuNYVN5JVgmW6yizUdQqVoJBpJTkDKiTVVJuEWQsyWaD4tGu8C8Hbutz5plN-XxIoj4LKo6DyLGgqPJwKu1F3tjrj_0aSA_vaX4I</recordid><startdate>20171208</startdate><enddate>20171208</enddate><creator>Zhang, Li</creator><creator>Kong, Guoguo</creator><creator>Meng, Yaping</creator><creator>Tian, Jinshu</creator><creator>Zhang, Lijie</creator><creator>Wan, Shaolong</creator><creator>Lin, Jingdong</creator><creator>Wang, Yong</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-0686-6908</orcidid><orcidid>https://orcid.org/0000-0002-8460-7410</orcidid></search><sort><creationdate>20171208</creationdate><title>Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels</title><author>Zhang, Li ; Kong, Guoguo ; Meng, Yaping ; Tian, Jinshu ; Zhang, Lijie ; Wan, Shaolong ; Lin, Jingdong ; Wang, Yong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1075-1a98b1602c618c62b15bbd5c84d649bd9e0ff70d6209ba85402682b2bc34ee083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Carbon Dioxide - chemistry</topic><topic>Catalysis</topic><topic>Hot Temperature</topic><topic>Hydrogen - chemistry</topic><topic>Hydrogenation</topic><topic>Photochemical Processes</topic><topic>Photolysis</topic><topic>Solar Energy</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Li</creatorcontrib><creatorcontrib>Kong, Guoguo</creatorcontrib><creatorcontrib>Meng, Yaping</creatorcontrib><creatorcontrib>Tian, Jinshu</creatorcontrib><creatorcontrib>Zhang, Lijie</creatorcontrib><creatorcontrib>Wan, Shaolong</creatorcontrib><creatorcontrib>Lin, Jingdong</creatorcontrib><creatorcontrib>Wang, Yong</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Li</au><au>Kong, Guoguo</au><au>Meng, Yaping</au><au>Tian, Jinshu</au><au>Zhang, Lijie</au><au>Wan, Shaolong</au><au>Lin, Jingdong</au><au>Wang, Yong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2017-12-08</date><risdate>2017</risdate><volume>10</volume><issue>23</issue><spage>4709</spage><epage>4714</epage><pages>4709-4714</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Photocatalytic CO
reduction into renewable hydrocarbon solar fuels is considered as a promising strategy to simultaneously address global energy and environmental issues. This study focused on the direct coupling of photocatalytic water splitting and thermocatalytic hydrogenation of CO
in the conversion of CO
-H
O into fuels. Specifically, it was found that direct coupling of thermo- and photocatalysis over Au-Ru/TiO
leads to activity 15 times higher (T=358 K; ca. 99 % CH
selectivity) in the conversion of CO
-H
O into fuels than that of photocatalytic water splitting. This is ascribed to the promoting effect of thermocatalytic hydrogenation of CO
by hydrogen atoms generated in situ by photocatalytic water splitting.</abstract><cop>Germany</cop><pmid>29045065</pmid><doi>10.1002/cssc.201701472</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-0686-6908</orcidid><orcidid>https://orcid.org/0000-0002-8460-7410</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1864-5631 |
| ispartof | ChemSusChem, 2017-12, Vol.10 (23), p.4709-4714 |
| issn | 1864-5631 1864-564X |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_cssc_201701472 |
| source | MEDLINE; Access via Wiley Online Library |
| subjects | Carbon Dioxide - chemistry Catalysis Hot Temperature Hydrogen - chemistry Hydrogenation Photochemical Processes Photolysis Solar Energy Water |
| title | Direct Coupling of Thermo- and Photocatalysis for Conversion of CO 2 -H 2 O into Fuels |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T17%3A09%3A51IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Direct%20Coupling%20of%20Thermo-%20and%20Photocatalysis%20for%20Conversion%20of%20CO%202%20-H%202%20O%20into%20Fuels&rft.jtitle=ChemSusChem&rft.au=Zhang,%20Li&rft.date=2017-12-08&rft.volume=10&rft.issue=23&rft.spage=4709&rft.epage=4714&rft.pages=4709-4714&rft.issn=1864-5631&rft.eissn=1864-564X&rft_id=info:doi/10.1002/cssc.201701472&rft_dat=%3Cpubmed_cross%3E29045065%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/29045065&rfr_iscdi=true |