Synthesis of radial‐like ZnO structure by hydrothermal method with ZnSO 4 ·7H 2 O and Zn(CH 3 COO) 2 ·2H 2 O as zinc sources

Radial‐like ZnO structures were prepared using zinc sulfate (ZnSO 4 ·7H 2 O) and zinc acetate [Zn(CH 3 COO) 2 ·2H 2 O] as zinc sources by a facile template‐free hydrothermal method in this paper. Structural and optical properties of radial‐like ZnO structures are characterized by X‐ray diffraction (XRD), field emission scanning electron microscopy (FESEM), UV‐vis spectrophotometer and photoluminescence measurement (PL). It has been found that the distinct surface morphologies of radial‐like ZnO structures grown by different zinc sources. Slim radial‐like ZnO with a hexagonal wurtzite structure is grown by using ZnSO 4 ·7H 2 O as zinc sources, whereas coarse radial‐like ZnO with zincite structure is achieved by zinc acetate. The UV‐vis absorption spectra of them both display an obvious and significant absorption in the ultraviolet region. The room temperature PL spectra of ZnO structures grown by two different zinc sources possess a common feature that consists of a strong ultraviolet (UV) peak and visible emission band.