Implications for the Hydrogenation of Propyne and Propene with Parahydrogen due to the in situ Transformation of Rh 2 C to Rh 0 /C

NMR spectroscopy studies using parahydrogen-induced polarization have previously established the existence of the pairwise hydrogen addition route in the hydrogenation of unsaturated hydrocarbons over heterogeneous catalysts, including those based on rhodium (Rh ). This pathway requires the incorpor...

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Veröffentlicht in:Chemphyschem 2024-09, Vol.25 (17), p.e202400270
Hauptverfasser: Pokochueva, Ekaterina V, Kountoupi, Evgenia, Janák, Marcel, Kuznetsov, Denis A, Prosvirin, Igor P, Müller, Christoph R, Fedorov, Alexey, Koptyug, Igor V
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Sprache:eng
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