Application of a Newly Synthesized Calixarene in Metal Ions Extraction
A new ligand, 25,27‐bis (3‐(4′‐biphenyl‐4‐hydroxy carboxylic acid) propoxy)‐26,28‐dihydroxy‐5,11,17‐tetra(tert‐butyl)calix[4]arene (CBiPh), a derivative of p‐tert‐butylcalix[4]arene (Cax) that was functionalized at the lower rim with biphenyl carboxylic acid has been synthesized. The compound was ch...
Gespeichert in:
| Veröffentlicht in: | Clean : soil, air, water air, water, 2008-06, Vol.36 (5-6), p.498-503 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 503 |
|---|---|
| container_issue | 5-6 |
| container_start_page | 498 |
| container_title | Clean : soil, air, water |
| container_volume | 36 |
| creator | Hamid, Shafida Abd Tarmizi, Amirah Amalina Ahmad Mohamad Ali, Abdussalam Salhin Saad, Bahruddin |
| description | A new ligand, 25,27‐bis (3‐(4′‐biphenyl‐4‐hydroxy carboxylic acid) propoxy)‐26,28‐dihydroxy‐5,11,17‐tetra(tert‐butyl)calix[4]arene (CBiPh), a derivative of p‐tert‐butylcalix[4]arene (Cax) that was functionalized at the lower rim with biphenyl carboxylic acid has been synthesized. The compound was characterized by using NMR, FT‐IR, and elemental analysis. The 1H and 13C NMR studies indicate that this new macrocycle (CBiPh) preferably adopts a cone structure. Sorbent materials prepared by immobilizing the ligands into silica sol–gel matrix (referred to as calixarene immobilized with sorbent (Cax‐SG) and CBiPh immobilized with sorbent (CBiPh‐SG)) were studied for their competitive sorption characteristic of a mixture of twelve metal ions (Mg2+, Li+, Cd2+, Co2+, Pb2+, Ca2+, Ba2+, Rb+, Ag+, Cs+, Sr2+, and Hg2+). Under the adopted conditions, both sorbents exhibited highest selectivity toward Ag+ (70% for Cax‐SG and 85% CBiPh‐SG), followed by Hg2+ (60% for Cax‐SG and 65% CBiPh‐SG) while the other metal ions were negligibly extracted ( |
| doi_str_mv | 10.1002/clen.200800065 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_clen_200800065</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>CLEN200800065</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3275-e1e4d33fac87f091cc3f7ca6d48690a28fe6839efae9d50de0dfa3b35cd66bf63</originalsourceid><addsrcrecordid>eNqF0L1OwzAUBWALgUQprMx-gZTruHaSsYraUihB4kcdLde5FgaTVHYkGp6eVkUVG9O9w_nOcAi5ZjBiAOmN8diMUoAcAKQ4IQOWS56AlMXp8RdwTi5ifN8lgEk2ILPJZuOd0Z1rG9paqmmFX76nz33TvWF031jTUnu31QEbpK6hD9hpTxdtE-l02wVt9vSSnFntI1793iF5nU1fyttk-ThflJNlYniaiQQZjmvOrTZ5ZqFgxnCbGS3rcS4L0GluUea8QKuxqAXUCLXVfM2FqaVcW8mHZHToNaGNMaBVm-A-degVA7VfQe1XUMcVdqA4gC_nsf8nrcrltPprk4N1scPt0erwoWTGM6FW1Vw9sbvqPmMrJfgP5p5xcA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Application of a Newly Synthesized Calixarene in Metal Ions Extraction</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Hamid, Shafida Abd ; Tarmizi, Amirah Amalina Ahmad ; Mohamad Ali, Abdussalam Salhin ; Saad, Bahruddin</creator><creatorcontrib>Hamid, Shafida Abd ; Tarmizi, Amirah Amalina Ahmad ; Mohamad Ali, Abdussalam Salhin ; Saad, Bahruddin</creatorcontrib><description>A new ligand, 25,27‐bis (3‐(4′‐biphenyl‐4‐hydroxy carboxylic acid) propoxy)‐26,28‐dihydroxy‐5,11,17‐tetra(tert‐butyl)calix[4]arene (CBiPh), a derivative of p‐tert‐butylcalix[4]arene (Cax) that was functionalized at the lower rim with biphenyl carboxylic acid has been synthesized. The compound was characterized by using NMR, FT‐IR, and elemental analysis. The 1H and 13C NMR studies indicate that this new macrocycle (CBiPh) preferably adopts a cone structure. Sorbent materials prepared by immobilizing the ligands into silica sol–gel matrix (referred to as calixarene immobilized with sorbent (Cax‐SG) and CBiPh immobilized with sorbent (CBiPh‐SG)) were studied for their competitive sorption characteristic of a mixture of twelve metal ions (Mg2+, Li+, Cd2+, Co2+, Pb2+, Ca2+, Ba2+, Rb+, Ag+, Cs+, Sr2+, and Hg2+). Under the adopted conditions, both sorbents exhibited highest selectivity toward Ag+ (70% for Cax‐SG and 85% CBiPh‐SG), followed by Hg2+ (60% for Cax‐SG and 65% CBiPh‐SG) while the other metal ions were negligibly extracted (< 20%).
Research Article: A new carboxyl derivative of p‐tert‐butylcalix[4]arene is synthesized and its capabilities for extraction of metal ions is evaluated. A key difference to so far published work is the competitive sorption characteristic where a mixture containing 12 metal ions was investigated.</description><identifier>ISSN: 1863-0650</identifier><identifier>EISSN: 1863-0669</identifier><identifier>DOI: 10.1002/clen.200800065</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Calixarene ; Metal ions ; Sol-gel ; Sorbent ; Synthesis</subject><ispartof>Clean : soil, air, water, 2008-06, Vol.36 (5-6), p.498-503</ispartof><rights>Copyright © 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3275-e1e4d33fac87f091cc3f7ca6d48690a28fe6839efae9d50de0dfa3b35cd66bf63</citedby><cites>FETCH-LOGICAL-c3275-e1e4d33fac87f091cc3f7ca6d48690a28fe6839efae9d50de0dfa3b35cd66bf63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fclen.200800065$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fclen.200800065$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Hamid, Shafida Abd</creatorcontrib><creatorcontrib>Tarmizi, Amirah Amalina Ahmad</creatorcontrib><creatorcontrib>Mohamad Ali, Abdussalam Salhin</creatorcontrib><creatorcontrib>Saad, Bahruddin</creatorcontrib><title>Application of a Newly Synthesized Calixarene in Metal Ions Extraction</title><title>Clean : soil, air, water</title><addtitle>Clean Soil Air Water</addtitle><description>A new ligand, 25,27‐bis (3‐(4′‐biphenyl‐4‐hydroxy carboxylic acid) propoxy)‐26,28‐dihydroxy‐5,11,17‐tetra(tert‐butyl)calix[4]arene (CBiPh), a derivative of p‐tert‐butylcalix[4]arene (Cax) that was functionalized at the lower rim with biphenyl carboxylic acid has been synthesized. The compound was characterized by using NMR, FT‐IR, and elemental analysis. The 1H and 13C NMR studies indicate that this new macrocycle (CBiPh) preferably adopts a cone structure. Sorbent materials prepared by immobilizing the ligands into silica sol–gel matrix (referred to as calixarene immobilized with sorbent (Cax‐SG) and CBiPh immobilized with sorbent (CBiPh‐SG)) were studied for their competitive sorption characteristic of a mixture of twelve metal ions (Mg2+, Li+, Cd2+, Co2+, Pb2+, Ca2+, Ba2+, Rb+, Ag+, Cs+, Sr2+, and Hg2+). Under the adopted conditions, both sorbents exhibited highest selectivity toward Ag+ (70% for Cax‐SG and 85% CBiPh‐SG), followed by Hg2+ (60% for Cax‐SG and 65% CBiPh‐SG) while the other metal ions were negligibly extracted (< 20%).
Research Article: A new carboxyl derivative of p‐tert‐butylcalix[4]arene is synthesized and its capabilities for extraction of metal ions is evaluated. A key difference to so far published work is the competitive sorption characteristic where a mixture containing 12 metal ions was investigated.</description><subject>Calixarene</subject><subject>Metal ions</subject><subject>Sol-gel</subject><subject>Sorbent</subject><subject>Synthesis</subject><issn>1863-0650</issn><issn>1863-0669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqF0L1OwzAUBWALgUQprMx-gZTruHaSsYraUihB4kcdLde5FgaTVHYkGp6eVkUVG9O9w_nOcAi5ZjBiAOmN8diMUoAcAKQ4IQOWS56AlMXp8RdwTi5ifN8lgEk2ILPJZuOd0Z1rG9paqmmFX76nz33TvWF031jTUnu31QEbpK6hD9hpTxdtE-l02wVt9vSSnFntI1793iF5nU1fyttk-ThflJNlYniaiQQZjmvOrTZ5ZqFgxnCbGS3rcS4L0GluUea8QKuxqAXUCLXVfM2FqaVcW8mHZHToNaGNMaBVm-A-degVA7VfQe1XUMcVdqA4gC_nsf8nrcrltPprk4N1scPt0erwoWTGM6FW1Vw9sbvqPmMrJfgP5p5xcA</recordid><startdate>200806</startdate><enddate>200806</enddate><creator>Hamid, Shafida Abd</creator><creator>Tarmizi, Amirah Amalina Ahmad</creator><creator>Mohamad Ali, Abdussalam Salhin</creator><creator>Saad, Bahruddin</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200806</creationdate><title>Application of a Newly Synthesized Calixarene in Metal Ions Extraction</title><author>Hamid, Shafida Abd ; Tarmizi, Amirah Amalina Ahmad ; Mohamad Ali, Abdussalam Salhin ; Saad, Bahruddin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3275-e1e4d33fac87f091cc3f7ca6d48690a28fe6839efae9d50de0dfa3b35cd66bf63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Calixarene</topic><topic>Metal ions</topic><topic>Sol-gel</topic><topic>Sorbent</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hamid, Shafida Abd</creatorcontrib><creatorcontrib>Tarmizi, Amirah Amalina Ahmad</creatorcontrib><creatorcontrib>Mohamad Ali, Abdussalam Salhin</creatorcontrib><creatorcontrib>Saad, Bahruddin</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Clean : soil, air, water</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hamid, Shafida Abd</au><au>Tarmizi, Amirah Amalina Ahmad</au><au>Mohamad Ali, Abdussalam Salhin</au><au>Saad, Bahruddin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of a Newly Synthesized Calixarene in Metal Ions Extraction</atitle><jtitle>Clean : soil, air, water</jtitle><addtitle>Clean Soil Air Water</addtitle><date>2008-06</date><risdate>2008</risdate><volume>36</volume><issue>5-6</issue><spage>498</spage><epage>503</epage><pages>498-503</pages><issn>1863-0650</issn><eissn>1863-0669</eissn><abstract>A new ligand, 25,27‐bis (3‐(4′‐biphenyl‐4‐hydroxy carboxylic acid) propoxy)‐26,28‐dihydroxy‐5,11,17‐tetra(tert‐butyl)calix[4]arene (CBiPh), a derivative of p‐tert‐butylcalix[4]arene (Cax) that was functionalized at the lower rim with biphenyl carboxylic acid has been synthesized. The compound was characterized by using NMR, FT‐IR, and elemental analysis. The 1H and 13C NMR studies indicate that this new macrocycle (CBiPh) preferably adopts a cone structure. Sorbent materials prepared by immobilizing the ligands into silica sol–gel matrix (referred to as calixarene immobilized with sorbent (Cax‐SG) and CBiPh immobilized with sorbent (CBiPh‐SG)) were studied for their competitive sorption characteristic of a mixture of twelve metal ions (Mg2+, Li+, Cd2+, Co2+, Pb2+, Ca2+, Ba2+, Rb+, Ag+, Cs+, Sr2+, and Hg2+). Under the adopted conditions, both sorbents exhibited highest selectivity toward Ag+ (70% for Cax‐SG and 85% CBiPh‐SG), followed by Hg2+ (60% for Cax‐SG and 65% CBiPh‐SG) while the other metal ions were negligibly extracted (< 20%).
Research Article: A new carboxyl derivative of p‐tert‐butylcalix[4]arene is synthesized and its capabilities for extraction of metal ions is evaluated. A key difference to so far published work is the competitive sorption characteristic where a mixture containing 12 metal ions was investigated.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/clen.200800065</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1863-0650 |
| ispartof | Clean : soil, air, water, 2008-06, Vol.36 (5-6), p.498-503 |
| issn | 1863-0650 1863-0669 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_clen_200800065 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Calixarene Metal ions Sol-gel Sorbent Synthesis |
| title | Application of a Newly Synthesized Calixarene in Metal Ions Extraction |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T04%3A15%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Application%20of%20a%20Newly%20Synthesized%20Calixarene%20in%20Metal%20Ions%20Extraction&rft.jtitle=Clean%20:%20soil,%20air,%20water&rft.au=Hamid,%20Shafida%20Abd&rft.date=2008-06&rft.volume=36&rft.issue=5-6&rft.spage=498&rft.epage=503&rft.pages=498-503&rft.issn=1863-0650&rft.eissn=1863-0669&rft_id=info:doi/10.1002/clen.200800065&rft_dat=%3Cwiley_cross%3ECLEN200800065%3C/wiley_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |