A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties
The precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO 4 2– anion released by in‐situ decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni 24 P...
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| Veröffentlicht in: | Chinese journal of chemistry 2024-10, Vol.42 (20), p.2438-2444 |
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| creator | Fan, Caihong Bai, Kaipeng Luo, Qiancheng Han, Tian Huang, Chang Zheng, Yanzhen Chen, Weipeng |
| description | The precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO
4
2–
anion released by
in‐situ
decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni
24
Pr
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·16H
2
O·25CH
3
OH (
1
, H
2
pida =
N
‐phenyliminodiacetic acid), [Ni
24
Nd
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·14H
2
O·24CH
3
OH (
2
) and [Ni
24
Gd
22
(μ
3
‐OH)
36
(bida)
24
(SO
4
)
7
(NO
3
)
3
(CH
3
COO)
3
]·(SO
4
)·Br
4
·(NO
3
)
4
·31H
2
O·32CH
3
OH (
3
, H
2
bida =
N
‐benzyliminodiacetic acid), have been successfully isolated. X‐ray crystal structure analyses reveal that all the cationic {Ni
24
RE
22
} cores in
1
—
3
possess a ball‐like structure with
C
3
v
symmetry, and can be viewed as consisting of an inner {RE
22
} core and an outer {Ni
24
} shell. From
1
and
2
to
3
, due to the lanthanide contraction effect, the coordination numbers for rare‐earth metal centers in {RE
22
} are different, resulting in different number of SO
4
2–
and NO
3
–
anions to support and stabilize the skeleton structures. Meanwhile, the magnetic properties of complexes
1
—
3
were also studied. The result revealed that complexes
1
—
3
show antiferromagnetic/ferrimagnetic interactions, and
3
exhibits magneto‐caloric effect at ultralow temperatures with a maximum –Δ
S
m
(magnetic entropy change) value of 33.03 J·kg
−1
·K
−1
at 3.0 K and 7 T. |
| doi_str_mv | 10.1002/cjoc.202400262 |
| format | Article |
| fullrecord | <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_cjoc_202400262</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_cjoc_202400262</sourcerecordid><originalsourceid>FETCH-crossref_primary_10_1002_cjoc_2024002623</originalsourceid><addsrcrecordid>eNqVj81KAzEUhYMoWKtb1_cBnDFJYwbcSbF0YxWmi-5CyNxpUzI_JBlkXPkIgm_okzQD4t7F5XwHzl18hNwymjNK-b05dibnlItUJD8jMyaZyAoqH84TU8oyScXuklyFcEyTouByRj6eYIPvsNKNdSN0NZSvIIDDz-d3uq8tNr3TEStYVKmKGtZ2f0i0GYxD7W0cYemGENGHRyjHNh4wYLiDMvrBxMFPrNsKXvS-xWgNvPmuRx8thmtyUWsX8OY35yRfPW-X68z4LgSPteq9bbQfFaNqMlSTofozXPz74QQBL1xs</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Fan, Caihong ; Bai, Kaipeng ; Luo, Qiancheng ; Han, Tian ; Huang, Chang ; Zheng, Yanzhen ; Chen, Weipeng</creator><creatorcontrib>Fan, Caihong ; Bai, Kaipeng ; Luo, Qiancheng ; Han, Tian ; Huang, Chang ; Zheng, Yanzhen ; Chen, Weipeng</creatorcontrib><description>The precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO
4
2–
anion released by
in‐situ
decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni
24
Pr
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·16H
2
O·25CH
3
OH (
1
, H
2
pida =
N
‐phenyliminodiacetic acid), [Ni
24
Nd
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·14H
2
O·24CH
3
OH (
2
) and [Ni
24
Gd
22
(μ
3
‐OH)
36
(bida)
24
(SO
4
)
7
(NO
3
)
3
(CH
3
COO)
3
]·(SO
4
)·Br
4
·(NO
3
)
4
·31H
2
O·32CH
3
OH (
3
, H
2
bida =
N
‐benzyliminodiacetic acid), have been successfully isolated. X‐ray crystal structure analyses reveal that all the cationic {Ni
24
RE
22
} cores in
1
—
3
possess a ball‐like structure with
C
3
v
symmetry, and can be viewed as consisting of an inner {RE
22
} core and an outer {Ni
24
} shell. From
1
and
2
to
3
, due to the lanthanide contraction effect, the coordination numbers for rare‐earth metal centers in {RE
22
} are different, resulting in different number of SO
4
2–
and NO
3
–
anions to support and stabilize the skeleton structures. Meanwhile, the magnetic properties of complexes
1
—
3
were also studied. The result revealed that complexes
1
—
3
show antiferromagnetic/ferrimagnetic interactions, and
3
exhibits magneto‐caloric effect at ultralow temperatures with a maximum –Δ
S
m
(magnetic entropy change) value of 33.03 J·kg
−1
·K
−1
at 3.0 K and 7 T.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.202400262</identifier><language>eng</language><ispartof>Chinese journal of chemistry, 2024-10, Vol.42 (20), p.2438-2444</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-crossref_primary_10_1002_cjoc_2024002623</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Fan, Caihong</creatorcontrib><creatorcontrib>Bai, Kaipeng</creatorcontrib><creatorcontrib>Luo, Qiancheng</creatorcontrib><creatorcontrib>Han, Tian</creatorcontrib><creatorcontrib>Huang, Chang</creatorcontrib><creatorcontrib>Zheng, Yanzhen</creatorcontrib><creatorcontrib>Chen, Weipeng</creatorcontrib><title>A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties</title><title>Chinese journal of chemistry</title><description>The precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO
4
2–
anion released by
in‐situ
decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni
24
Pr
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·16H
2
O·25CH
3
OH (
1
, H
2
pida =
N
‐phenyliminodiacetic acid), [Ni
24
Nd
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·14H
2
O·24CH
3
OH (
2
) and [Ni
24
Gd
22
(μ
3
‐OH)
36
(bida)
24
(SO
4
)
7
(NO
3
)
3
(CH
3
COO)
3
]·(SO
4
)·Br
4
·(NO
3
)
4
·31H
2
O·32CH
3
OH (
3
, H
2
bida =
N
‐benzyliminodiacetic acid), have been successfully isolated. X‐ray crystal structure analyses reveal that all the cationic {Ni
24
RE
22
} cores in
1
—
3
possess a ball‐like structure with
C
3
v
symmetry, and can be viewed as consisting of an inner {RE
22
} core and an outer {Ni
24
} shell. From
1
and
2
to
3
, due to the lanthanide contraction effect, the coordination numbers for rare‐earth metal centers in {RE
22
} are different, resulting in different number of SO
4
2–
and NO
3
–
anions to support and stabilize the skeleton structures. Meanwhile, the magnetic properties of complexes
1
—
3
were also studied. The result revealed that complexes
1
—
3
show antiferromagnetic/ferrimagnetic interactions, and
3
exhibits magneto‐caloric effect at ultralow temperatures with a maximum –Δ
S
m
(magnetic entropy change) value of 33.03 J·kg
−1
·K
−1
at 3.0 K and 7 T.</description><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqVj81KAzEUhYMoWKtb1_cBnDFJYwbcSbF0YxWmi-5CyNxpUzI_JBlkXPkIgm_okzQD4t7F5XwHzl18hNwymjNK-b05dibnlItUJD8jMyaZyAoqH84TU8oyScXuklyFcEyTouByRj6eYIPvsNKNdSN0NZSvIIDDz-d3uq8tNr3TEStYVKmKGtZ2f0i0GYxD7W0cYemGENGHRyjHNh4wYLiDMvrBxMFPrNsKXvS-xWgNvPmuRx8thmtyUWsX8OY35yRfPW-X68z4LgSPteq9bbQfFaNqMlSTofozXPz74QQBL1xs</recordid><startdate>20241015</startdate><enddate>20241015</enddate><creator>Fan, Caihong</creator><creator>Bai, Kaipeng</creator><creator>Luo, Qiancheng</creator><creator>Han, Tian</creator><creator>Huang, Chang</creator><creator>Zheng, Yanzhen</creator><creator>Chen, Weipeng</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20241015</creationdate><title>A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties</title><author>Fan, Caihong ; Bai, Kaipeng ; Luo, Qiancheng ; Han, Tian ; Huang, Chang ; Zheng, Yanzhen ; Chen, Weipeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-crossref_primary_10_1002_cjoc_2024002623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fan, Caihong</creatorcontrib><creatorcontrib>Bai, Kaipeng</creatorcontrib><creatorcontrib>Luo, Qiancheng</creatorcontrib><creatorcontrib>Han, Tian</creatorcontrib><creatorcontrib>Huang, Chang</creatorcontrib><creatorcontrib>Zheng, Yanzhen</creatorcontrib><creatorcontrib>Chen, Weipeng</creatorcontrib><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fan, Caihong</au><au>Bai, Kaipeng</au><au>Luo, Qiancheng</au><au>Han, Tian</au><au>Huang, Chang</au><au>Zheng, Yanzhen</au><au>Chen, Weipeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties</atitle><jtitle>Chinese journal of chemistry</jtitle><date>2024-10-15</date><risdate>2024</risdate><volume>42</volume><issue>20</issue><spage>2438</spage><epage>2444</epage><pages>2438-2444</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>The precise syntheses of transition–rare‐earth metal clusters with desired structures remain a great challenge. Herein, by utilizing SO
4
2–
anion released by
in‐situ
decomposition of sodium dodecyl sulfate (SDS) as a template, a series of novel high‐nuclearity 3d‐4f clusters, formulated as [Ni
24
Pr
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·16H
2
O·25CH
3
OH (
1
, H
2
pida =
N
‐phenyliminodiacetic acid), [Ni
24
Nd
22
(μ
3
‐OH)
31
(pida)
24
(SO
4
)
4
(NO
3
)
9
(CH
3
COO)
3
]·Br
4
·(NO
3
)
11
·14H
2
O·24CH
3
OH (
2
) and [Ni
24
Gd
22
(μ
3
‐OH)
36
(bida)
24
(SO
4
)
7
(NO
3
)
3
(CH
3
COO)
3
]·(SO
4
)·Br
4
·(NO
3
)
4
·31H
2
O·32CH
3
OH (
3
, H
2
bida =
N
‐benzyliminodiacetic acid), have been successfully isolated. X‐ray crystal structure analyses reveal that all the cationic {Ni
24
RE
22
} cores in
1
—
3
possess a ball‐like structure with
C
3
v
symmetry, and can be viewed as consisting of an inner {RE
22
} core and an outer {Ni
24
} shell. From
1
and
2
to
3
, due to the lanthanide contraction effect, the coordination numbers for rare‐earth metal centers in {RE
22
} are different, resulting in different number of SO
4
2–
and NO
3
–
anions to support and stabilize the skeleton structures. Meanwhile, the magnetic properties of complexes
1
—
3
were also studied. The result revealed that complexes
1
—
3
show antiferromagnetic/ferrimagnetic interactions, and
3
exhibits magneto‐caloric effect at ultralow temperatures with a maximum –Δ
S
m
(magnetic entropy change) value of 33.03 J·kg
−1
·K
−1
at 3.0 K and 7 T.</abstract><doi>10.1002/cjoc.202400262</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1001-604X |
| ispartof | Chinese journal of chemistry, 2024-10, Vol.42 (20), p.2438-2444 |
| issn | 1001-604X 1614-7065 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_cjoc_202400262 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | A New Family of SO 4 2 – ‐Templated 3d‐4f High‐Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-18T14%3A28%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20New%20Family%20of%20SO%204%202%20%E2%80%93%20%E2%80%90Templated%203d%E2%80%904f%20High%E2%80%90Nuclearity%20Clusters:%20Syntheses,%20Structures,%20and%20Magnetic%20Properties&rft.jtitle=Chinese%20journal%20of%20chemistry&rft.au=Fan,%20Caihong&rft.date=2024-10-15&rft.volume=42&rft.issue=20&rft.spage=2438&rft.epage=2444&rft.pages=2438-2444&rft.issn=1001-604X&rft.eissn=1614-7065&rft_id=info:doi/10.1002/cjoc.202400262&rft_dat=%3Ccrossref%3E10_1002_cjoc_202400262%3C/crossref%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |