PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization
A new amphiphilic graft copolymer containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. Grafting‐from str...
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| Veröffentlicht in: | Chinese journal of chemistry 2009-11, Vol.27 (11), p.2273-2278 |
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| container_title | Chinese journal of chemistry |
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| creator | Zhang, Xiaohuan Wang, Beidi Yang, Dong Zhang, Xiaohong Yuan, Li Tang, Qianqian Hu, Jianhua |
| description | A new amphiphilic graft copolymer containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. Grafting‐from strategy was employed to synthesize PMOMA‐g‐PVAc graft copolymer (Mw/Mn=1.64) via ATRP. The final PAA‐g‐PVAc amphiphilic graft copolymer was obtained by selective acidic hydrolysis of PMOMA backbone in acidic environment without affecting the side chains. The critical micelle concentrations (cmc) in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.
A new amphiphilic graft copolymer (PAA‐g‐PVAc) containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. The critical micelle concentrations (cmc) of PAA‐g‐PVAc in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres. |
| doi_str_mv | 10.1002/cjoc.200990381 |
| format | Article |
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A new amphiphilic graft copolymer (PAA‐g‐PVAc) containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. The critical micelle concentrations (cmc) of PAA‐g‐PVAc in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.</description><identifier>ISSN: 1001-604X</identifier><identifier>EISSN: 1614-7065</identifier><identifier>DOI: 10.1002/cjoc.200990381</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>amphiphilic ; ATRP ; graft copolymer ; grafting-from ; synthesis</subject><ispartof>Chinese journal of chemistry, 2009-11, Vol.27 (11), p.2273-2278</ispartof><rights>Copyright © 2009 SIOC, CAS, Shanghai & WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3271-b6587e6badb0b5ef118fc8585dfb08a0173f369c25f0cfa86101ff38d47007143</citedby><cites>FETCH-LOGICAL-c3271-b6587e6badb0b5ef118fc8585dfb08a0173f369c25f0cfa86101ff38d47007143</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcjoc.200990381$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcjoc.200990381$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Zhang, Xiaohuan</creatorcontrib><creatorcontrib>Wang, Beidi</creatorcontrib><creatorcontrib>Yang, Dong</creatorcontrib><creatorcontrib>Zhang, Xiaohong</creatorcontrib><creatorcontrib>Yuan, Li</creatorcontrib><creatorcontrib>Tang, Qianqian</creatorcontrib><creatorcontrib>Hu, Jianhua</creatorcontrib><title>PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization</title><title>Chinese journal of chemistry</title><addtitle>Chin. J. Chem</addtitle><description>A new amphiphilic graft copolymer containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. Grafting‐from strategy was employed to synthesize PMOMA‐g‐PVAc graft copolymer (Mw/Mn=1.64) via ATRP. The final PAA‐g‐PVAc amphiphilic graft copolymer was obtained by selective acidic hydrolysis of PMOMA backbone in acidic environment without affecting the side chains. The critical micelle concentrations (cmc) in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.
A new amphiphilic graft copolymer (PAA‐g‐PVAc) containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. The critical micelle concentrations (cmc) of PAA‐g‐PVAc in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.</description><subject>amphiphilic</subject><subject>ATRP</subject><subject>graft copolymer</subject><subject>grafting-from</subject><subject>synthesis</subject><issn>1001-604X</issn><issn>1614-7065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNqFkF1LwzAUhosoOKe3XvcPdJ40bZJelqJTmW508wNvQpomLrNdR1LQ7tfbURHvhAPnwPs-5-LxvEsEEwQQXslNIychQJIAZujIGyGCooACiY_7GwAFBKLXU-_MuU3fpzQkI-9tkabBe7B4TqWf1ru16acy0p9aoVs_a3ZN1dXK-stu266VM3tV-kXnp21T-ysrtk73YS5KI0XlL4ay2YvWNNtz70SLyqmLnz32nm6uV9ltMJtP77J0FkgcUhQUJGZUkUKUBRSx0ggxLVnM4lIXwAQgijUmiQxjDVILRhAgrTErIwpAUYTH3mT4K23jnFWa76yphe04An4www9m-K-ZHkgG4NNUqvunzbP7efaXDQbWuFZ9_bLCfnBCMY35y-OUJ1Ge50vG-AP-Bmevd28</recordid><startdate>200911</startdate><enddate>200911</enddate><creator>Zhang, Xiaohuan</creator><creator>Wang, Beidi</creator><creator>Yang, Dong</creator><creator>Zhang, Xiaohong</creator><creator>Yuan, Li</creator><creator>Tang, Qianqian</creator><creator>Hu, Jianhua</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>200911</creationdate><title>PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization</title><author>Zhang, Xiaohuan ; Wang, Beidi ; Yang, Dong ; Zhang, Xiaohong ; Yuan, Li ; Tang, Qianqian ; Hu, Jianhua</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3271-b6587e6badb0b5ef118fc8585dfb08a0173f369c25f0cfa86101ff38d47007143</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>amphiphilic</topic><topic>ATRP</topic><topic>graft copolymer</topic><topic>grafting-from</topic><topic>synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Xiaohuan</creatorcontrib><creatorcontrib>Wang, Beidi</creatorcontrib><creatorcontrib>Yang, Dong</creatorcontrib><creatorcontrib>Zhang, Xiaohong</creatorcontrib><creatorcontrib>Yuan, Li</creatorcontrib><creatorcontrib>Tang, Qianqian</creatorcontrib><creatorcontrib>Hu, Jianhua</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Chinese journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Xiaohuan</au><au>Wang, Beidi</au><au>Yang, Dong</au><au>Zhang, Xiaohong</au><au>Yuan, Li</au><au>Tang, Qianqian</au><au>Hu, Jianhua</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization</atitle><jtitle>Chinese journal of chemistry</jtitle><addtitle>Chin. J. Chem</addtitle><date>2009-11</date><risdate>2009</risdate><volume>27</volume><issue>11</issue><spage>2273</spage><epage>2278</epage><pages>2273-2278</pages><issn>1001-604X</issn><eissn>1614-7065</eissn><abstract>A new amphiphilic graft copolymer containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. Grafting‐from strategy was employed to synthesize PMOMA‐g‐PVAc graft copolymer (Mw/Mn=1.64) via ATRP. The final PAA‐g‐PVAc amphiphilic graft copolymer was obtained by selective acidic hydrolysis of PMOMA backbone in acidic environment without affecting the side chains. The critical micelle concentrations (cmc) in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.
A new amphiphilic graft copolymer (PAA‐g‐PVAc) containing hydrophilic poly(acrylic acid) backbone and hydrophobic poly(vinyl acetate) side chains was synthesized via sequential atom transfer radical polymerization (ATRP) followed by selective hydrolysis of poly(methoxymethyl acrylate) backbone. The critical micelle concentrations (cmc) of PAA‐g‐PVAc in aqueous media were determined by a fluorescence probe technique. The micelle morphologies were found to be spheres.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/cjoc.200990381</doi><tpages>6</tpages></addata></record> |
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| subjects | amphiphilic ATRP graft copolymer grafting-from synthesis |
| title | PAA-g-PVAc Amphiphilic Graft Copolymer Synthesized by Atom Transfer Radical Polymerization |
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