Effect of solvent on the free energy of activation of S N 2 reaction between phenacyl bromide and amines

The kinetics of S N 2 reaction between phenacyl bromide and various amines in 12 different solvents were studied. Solvent effects on the rate of this reaction and free energy of activation, Δ G # , were interpreted by applying the Abraham‐Kamlet‐Taft (AKT) equation. The solvent polarity (π 1 *), sol...

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Veröffentlicht in:Chinese journal of chemistry 2000-07, Vol.18 (4), p.608-613
Hauptverfasser: Asadollah, Nasehzadeh, Abbas, Chahardoli
Format: Artikel
Sprache:eng
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