Bridging the Analytical Gap Between Gas Treatment and Reactor Plants in Carbon2Chem

The use of purified process gases as feedstock for subsequent processes requires a detailed verification of the gas purity to ensure long lifetimes of applied catalysts. Herein, the analytical infrastructure for the measurements of the cleaned gases is presented. An overview of all sampling points f...

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Veröffentlicht in:Chemie ingenieur technik 2022-10, Vol.94 (10), p.1405-1412
Hauptverfasser: Hegen, Oliver, Salazar Gómez, Jorge Iván, Grünwald, Christina, Rettke, Alina, Sojka, Martha, Klucken, Christian, Pickenbrock, Jens, Filipp, Jan, Schlögl, Robert, Ruland, Holger
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container_end_page 1412
container_issue 10
container_start_page 1405
container_title Chemie ingenieur technik
container_volume 94
creator Hegen, Oliver
Salazar Gómez, Jorge Iván
Grünwald, Christina
Rettke, Alina
Sojka, Martha
Klucken, Christian
Pickenbrock, Jens
Filipp, Jan
Schlögl, Robert
Ruland, Holger
description The use of purified process gases as feedstock for subsequent processes requires a detailed verification of the gas purity to ensure long lifetimes of applied catalysts. Herein, the analytical infrastructure for the measurements of the cleaned gases is presented. An overview of all sampling points for the off‐ and on‐line analysis is given. The detailed decryption of the composition of the cleaned blast furnace gas, its main components as well as its traces are presented. Thereby, over 99 % of the overall signal strength of this complex gas matrix measured with a proton transfer reaction mass spectrometer with H3O+ as reagent ion could be revealed. Furthermore, by the example of the catalyst poison H2S, the necessity of monitoring continuously the gas matrix for certain compounds was proven. Analytics in the bigger picture. In this article the reasons why detailed gas analytics are essential for the success of Carbon2Chem® are presented and a deeper insight in the installed analytical infrastructure as well as its application is provided.
doi_str_mv 10.1002/cite.202200015
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subjects Carbon2Chem
Gas analysis
Mass spectrometry
Steel mill gases
Sulfur
title Bridging the Analytical Gap Between Gas Treatment and Reactor Plants in Carbon2Chem
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