ChemInform Abstract: Divergent Synthesis of α,γ‐Disubstituted γ‐Butyrolactones Through Diastereoselective Bromolactonization with Alkali Metal Bromide: Asymmetric Total Synthesis of (+)‐Dubiusamine C

The diastereoselective bromolactonization of α‐substituted 4‐pentenoic acids and 4‐pentenamides by oxidative umpolung of bromide ion using alkali metal bromide with Oxone is investigated.

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Veröffentlicht in:	ChemInform 2016-01, Vol.47 (5), p.no-no
Hauptverfasser:	Moriyama, Katsuhiko, Sugiue, Toru, Nishinohara, Chihiro, Togo, Hideo
Format:	Artikel
Sprache:	eng
Schlagworte:	diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) furan derivatives halogenation ring closure reactions, annulation reactions
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description	The diastereoselective bromolactonization of α‐substituted 4‐pentenoic acids and 4‐pentenamides by oxidative umpolung of bromide ion using alkali metal bromide with Oxone is investigated.
doi_str_mv	10.1002/chin.201605120
format	Article
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subjects	diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) furan derivatives halogenation ring closure reactions, annulation reactions
title	ChemInform Abstract: Divergent Synthesis of α,γ‐Disubstituted γ‐Butyrolactones Through Diastereoselective Bromolactonization with Alkali Metal Bromide: Asymmetric Total Synthesis of (+)‐Dubiusamine C
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