ChemInform Abstract: Reaction of α-Nitroacrylates with Acetylacetone

ChemInform Abstract: Reaction of α-Nitroacrylates with Acetylacetone

α‐Nitroacrylates (I) successfully react with acetylacetone in MeOH in the presence of MeONa to give addition products (III), which can undergo an intramolecular O‐alkylation accompanied with elimination of nitrous acid [→ (IV)].

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-12, Vol.43 (49), p.no-no
Hauptverfasser: Baichurina, L. V., Baichurin, R. I., Aboskalova, N. I., Zobacheva, M. M., Berestovitskaya, V. M.
Format: Artikel
Sprache:eng
Schlagworte:
addition reactions
furan derivatives
ring closure reactions
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Zusammenfassung:α‐Nitroacrylates (I) successfully react with acetylacetone in MeOH in the presence of MeONa to give addition products (III), which can undergo an intramolecular O‐alkylation accompanied with elimination of nitrous acid [→ (IV)].
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201249107