ChemInform Abstract: The First Example for the Asymmetric Synthesis of Allenes by the Doering-LaFlamme Allene Synthesis with Enantiopure Cyclopropylmagnesium Carbenoids
The three‐step approach to the allenes involves reaction of α,β‐unsaturated carbonyl compounds with optically active sulfoxide (II) followed by reduction to give cyclopropane derivatives.
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| Veröffentlicht in: | ChemInform 2011-09, Vol.42 (38), p.no-no |
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| container_issue | 38 |
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| container_title | ChemInform |
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| creator | Momochi, Hitoshi Noguchi, Takafumi Miyagawa, Toshifumi Ogawa, Naoki Tadokoro, Makoto Satoh, Tsuyoshi |
| description | The three‐step approach to the allenes involves reaction of α,β‐unsaturated carbonyl compounds with optically active sulfoxide (II) followed by reduction to give cyclopropane derivatives. |
| doi_str_mv | 10.1002/chin.201138065 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | allenes (acyclic compounds) allenes (benzene compounds) cyclopropane derivatives diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) |
| title | ChemInform Abstract: The First Example for the Asymmetric Synthesis of Allenes by the Doering-LaFlamme Allene Synthesis with Enantiopure Cyclopropylmagnesium Carbenoids |
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