ChemInform Abstract: Enantioselective Carbonyl-Ene Reactions of Trifluoropyruvate in Ionic Liquid via a Recyclable Indium(III)-Pybox Complex

Most of the reactions carried out in a mixture of ionic liquid and DCE proceed faster than those carried out in pure DCE with comparable or better yields and enantioselectivities of the resulting tertiary homoallylic alcohols in shorter reaction times.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2011-01, Vol.42 (3), p.no-no
Hauptverfasser:	Zhao, Jun Feng, Tan, Boon Hong, Zhu, Ming-Kui, Tjan, Teguh Budiono W., Loh, Teck Peng
Format:	Artikel
Sprache:	eng
Schlagworte:	C-C bond formation diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) hydroxycarboxylic acids (ether carboxylic acids) (acyclic compounds) and esters hydroxycarboxylic acids (ether carboxylic acids) and esters (benzene compounds)
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Beschreibung
Zusammenfassung:	Most of the reactions carried out in a mixture of ionic liquid and DCE proceed faster than those carried out in pure DCE with comparable or better yields and enantioselectivities of the resulting tertiary homoallylic alcohols in shorter reaction times.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201103025