ChemInform Abstract: Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation

ChemInform Abstract: Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation

[Pd(allyl)]BF4 (I), [Pd(allyl)(2,4‐hexadiene)]BF4 (II), and [Pd(MeCN)4](BF4)2 (III) catalyze the dehydrogenation of NH3BH3 most efficiently with a release of 2.0 equiv.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2010-10, Vol.41 (43), p.no-no
Hauptverfasser: Kim, Sung-Kwan, Han, Won-Sik, Kim, Tae-Jin, Kim, Tae-Young, Nam, Suk Woo, Mitoraj, Mariusz, Piekos, Lukasz, Michalak, Artur, Hwang, Son-Jong, Kang, Sang Ook
Format: Artikel
Sprache:eng
Schlagworte:
boron
boron, B
catalysts
heterogeneous catalysis
heterogeneous catalysis, catalysts
hydrogen
hydrogen, H
palladium
palladium, Pd
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Beschreibung
Zusammenfassung:[Pd(allyl)]BF4 (I), [Pd(allyl)(2,4‐hexadiene)]BF4 (II), and [Pd(MeCN)4](BF4)2 (III) catalyze the dehydrogenation of NH3BH3 most efficiently with a release of 2.0 equiv.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201043008