ChemInform Abstract: Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives
Treatment of α,β‐unsaturated ketones with the sulfonium salt (I) and the weak base Cs2CO3 results in efficient and stereoselective formation of cyclohexadiene epoxides like (III).
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| Veröffentlicht in: | ChemInform 2010-09, Vol.41 (38), p.no-no |
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| container_issue | 38 |
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| container_title | ChemInform |
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| creator | Zhu, Ben-Hu Zhou, Rui Zheng, Jun-Cheng Deng, Xian-Ming Sun, Xiu-Li Shen, Qi Tang, Yong |
| description | Treatment of α,β‐unsaturated ketones with the sulfonium salt (I) and the weak base Cs2CO3 results in efficient and stereoselective formation of cyclohexadiene epoxides like (III). |
| doi_str_mv | 10.1002/chin.201038103 |
| format | Article |
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| identifier | ISSN: 0931-7597 |
| ispartof | ChemInform, 2010-09, Vol.41 (38), p.no-no |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | cyclopropane derivatives diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) oxirane derivatives polyphenyl derivatives |
| title | ChemInform Abstract: Highly Selective Ylide-Initiated Michael Addition/Cyclization Reaction for Synthesis of Cyclohexadiene Epoxide and Vinylcyclopropane Derivatives |
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