Activation of CO 2 , CS 2 , and COS by α-Diimine-Stabilized Gallylenes

Several gallylenes [L GaM(THF) ] stabilized by an α-diimine ligand (L =[(2,6-iPr C H )NC(Ph)] ; M=Li, n=3, 3-Li; M=Na, n=4, 3-Na; M=K, n=1, 3-K) were prepared, which display diverse reactivities toward carbon dioxide and its sulfurized analogues. The reaction of 3 with CO yielded a trimeric carbonat...

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Veröffentlicht in:	Chemistry : a European journal 2025-01, Vol.31 (5), p.e202403652
Hauptverfasser:	Guo, Meng, Dong, Ben, Qu, Yao, Sun, Zhenzhou, Yang, Li, Wang, Yanchao, Fedushkin, Igor L, Yang, Xiao-Juan
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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