$The Best of Both Worlds: Combining the Power of MICs and WCAs to generate Stable and Crystalline Cr I -tetracarbonyl Complexes with π - ${{\bf \pi }-}$ Accepting Ligands$

The Best of Both Worlds: Combining the Power of MICs and WCAs to generate Stable and Crystalline Cr I -tetracarbonyl Complexes with π - ${{\bf \pi }-}$ Accepting Ligands

Here we present stable and crystalline chromium(I) tetracarbonyl complexes with pyridyl-MIC (MIC=mesoionic carbene) ligands and weakly coordinating anions (WCA=[Al(OR ) ] , R =C(CF ) and BAr =[B(Ar ) ] , Ar =3,5-(CF ) C H ). The complexes were fully characterized via crystallographic, spectroscopic...

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Veröffentlicht in:	Chemistry : a European journal 2023-09, Vol.29 (50), p.e202301205
Hauptverfasser:	Bens, Tobias, Walter, Robert R M, Beerhues, Julia, Schmitt, Manuel, Krossing, Ingo, Sarkar, Biprajit
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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