Cover Feature: Azole‐Directed Cobalt‐Catalyzed Asymmetric Hydrogenation of Alkenes (Chem. Eur. J. 44/2022)

With his hand holding the sail and his feet on the sailboard, the position of the windsurfer mimics the key strategy of this work: the activation of hydrogenated substrates by chelating coordination with cobalt. The surfer is the cobalt catalyst holding the sail to coordinate parazole, and with his...

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Veröffentlicht in:Chemistry : a European journal 2022-08, Vol.28 (44), p.n/a
Hauptverfasser: Jin, Yue, Zou, Yashi, Hu, Yanhua, Han, Yunxi, Zhang, Zhenfeng, Zhang, Wanbin
Format: Artikel
Sprache:eng
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Zusammenfassung:With his hand holding the sail and his feet on the sailboard, the position of the windsurfer mimics the key strategy of this work: the activation of hydrogenated substrates by chelating coordination with cobalt. The surfer is the cobalt catalyst holding the sail to coordinate parazole, and with his foot on the hydrogenated substrate board to coordinate the vinyl group. Bubbles in the seawater represent the main reagent of the reaction, hydrogen, the dolphin represents the hydrogenated product of this reaction, and the wind represents the bisphosphine ligand that promotes the catalytic activity. Overall, the picture shows that the reaction we developed is powerful like the sport of surfing. More information can be found in the Research Article by Z. Zhang, W. Zhang, and co‐workers (DOI: 10.1002/chem.202201517).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202202080