Merging Pd 0 /Pd II Redox and Pd II /Pd II Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes

Merging Pd 0 /Pd II Redox and Pd II /Pd II Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes

An allylarylation of electron-deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative cataly...

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Veröffentlicht in:Chemistry : a European journal 2021-03, Vol.27 (15), p.5035-5040
Hauptverfasser: Semba, Kazuhiko, Ohta, Naoki, Paulus, Fritz, Ohata, Masaki, Nakao, Yoshiaki
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container_issue 15
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container_title Chemistry : a European journal
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creator Semba, Kazuhiko
Ohta, Naoki
Paulus, Fritz
Ohata, Masaki
Nakao, Yoshiaki
description An allylarylation of electron-deficient alkenes with aryl boronates and allylic carbonates has been developed. This method allows access to a wide variety of carbon skeletons from readily available starting materials. Mechanistic studies indicate that this reaction is enabled by a cooperative catalysis based on merging Pd /Pd redox and Pd /Pd non-redox catalytic cycles.
doi_str_mv 10.1002/chem.202100075
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title Merging Pd 0 /Pd II Redox and Pd II /Pd II Non-redox Catalytic Cycles for the Allylarylation of Electron-Deficient Alkenes
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