Iron Catalyzed Double Bond Isomerization: Evidence for an Fe I /Fe III Catalytic Cycle

Iron-catalyzed isomerization of alkenes is reported using an iron(II) β-diketiminate pre-catalyst. The reaction proceeds with a catalytic amount of a hydride source, such as pinacol borane (HBpin) or ammonia borane (H N⋅BH ). Reactivity with both allyl arenes and aliphatic alkenes has been studied....

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Veröffentlicht in:	Chemistry : a European journal 2021-04, Vol.27 (19), p.5972-5977
Hauptverfasser:	Woof, Callum R, Durand, Derek J, Fey, Natalie, Richards, Emma, Webster, Ruth L
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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