Ca II , Yb II and Sm II Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio- and Chemoselective Consecutive Hydrophosphinations with PH 3

The first example of intermolecular hydrophosphination of styrene, 2-vinylpyridine and phenylacetylene with PH catalyzed by bis-(amido) complexes [(Me Si) N] M(NHC) (M=Ca, Yb, Sm) coordinated by NHC ligands is described. The reactions of styrene with PH proceed under mild conditions in quantitative...

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Veröffentlicht in:	Chemistry : a European journal 2019-01, Vol.25 (2), p.459-463
Hauptverfasser:	Lapshin, Ivan V, Basalov, Ivan V, Lyssenko, Konstantin A, Cherkasov, Anton V, Trifonov, Alexander A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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