Direct Observation of Confined I - ⋅⋅⋅I 2 ⋅⋅⋅I - Interactions in a Metal-Organic Framework: Iodine Capture and Sensing

Herein a strategy is reported for capturing and sensing iodine by strong I ⋅⋅⋅I ⋅⋅⋅I interaction, confined in a metal-organic framework, [Tb(Cu I )(ina) (DMF)] (1) (ina=isonicotinate). As revealed by single-crystal X-ray crystallography, the uptaken I molecules directly contact the {Cu I } chains, v...

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Veröffentlicht in:Chemistry : a European journal 2017-06, Vol.23 (35), p.8409-8413
Hauptverfasser: Hu, Yue-Qiao, Li, Mu-Qing, Wang, Yanyan, Zhang, Tao, Liao, Pei-Qin, Zheng, Zhiping, Chen, Xiao-Ming, Zheng, Yan-Zhen
Format: Artikel
Sprache:eng
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