MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis
A novel MnFe O -porous organic polymer (POP) nanocomposite was synthesized by a facile hydrothermal method and using the highly cross-linked N-rich benzene-benzylamine POP. The nanocomposite presented highly efficient photocatalytic performance in the hydrogen evolution reaction (HER) from pure wate...
Gespeichert in:
| Veröffentlicht in: | Chemistry : a European journal 2016-10, Vol.22 (44), p.15639-15644 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 15644 |
|---|---|
| container_issue | 44 |
| container_start_page | 15639 |
| container_title | Chemistry : a European journal |
| container_volume | 22 |
| creator | Dhanalaxmi, Karnekanti Yadav, Rajkumar Kundu, Sudipta K Reddy, Benjaram Mahipal Amoli, Vipin Sinha, Anil Kumar Mondal, John |
| description | A novel MnFe
O
-porous organic polymer (POP) nanocomposite was synthesized by a facile hydrothermal method and using the highly cross-linked N-rich benzene-benzylamine POP. The nanocomposite presented highly efficient photocatalytic performance in the hydrogen evolution reaction (HER) from pure water without addition of any sacrificial agent under one AM 1.5 G sunlight illumination. A photocatalytic activity of 6.12 mmol h
g
was achieved in the absence of any noble metal cocatalyst, which is the highest H
production rate reported for nonprecious metal catalysts. The photocatalytic performance of MnFe
O
-POP could be attributed to the intrinsic synergistic effects of manganese ferrite (MnFe
O
) nanoclusters interacting with the nitrogen dopant POP with a unique mesoporous nanoarchitecture and spatially confined growth of MnFe
O
in the interconnected POP network, leading to high visible-light absorption with fast electron transport. |
| doi_str_mv | 10.1002/chem.201603419 |
| format | Article |
| fullrecord | <record><control><sourceid>pubmed_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_chem_201603419</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>27595431</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1071-4d4c81d8e6bb4076e9471e6922a467e87b1eac93b279096cf011cbec2ad89ba93</originalsourceid><addsrcrecordid>eNo9kF1LwzAYhYMobk5vvZT8gc58NWm8G9OpMN1AZZclTd9ukfWDpEX67-2Y7urlwDnn5TwI3VIypYSwe7uDcsoIlYQLqs_QmMaMRlzJ-ByNiRYqkjHXI3QVwjchREvOL9GIqVjHgtMx-nmrFoAZXmGB301VW9-H1uwD3njTNJBjV2GD17Wvu4BXfmsqZwe570vwD3iGHyG4bTX4Zt7uXAu27TzgovZ4Y1rw0Uezd23rqi1e7-q2tmYo74ML1-iiGN7Azd-doK_F0-f8JVqunl_ns2VkKVE0ErmwCc0TkFkmiJIwLKIgNWNGSAWJyigYq3nGlB7G2YJQajOwzOSJzozmEzQ99lpfh-ChSBvvSuP7lJL0QDA9EExPBIfA3THQdFkJ-cn-j4z_AtrzbRo</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis</title><source>Wiley Online Library All Journals</source><creator>Dhanalaxmi, Karnekanti ; Yadav, Rajkumar ; Kundu, Sudipta K ; Reddy, Benjaram Mahipal ; Amoli, Vipin ; Sinha, Anil Kumar ; Mondal, John</creator><creatorcontrib>Dhanalaxmi, Karnekanti ; Yadav, Rajkumar ; Kundu, Sudipta K ; Reddy, Benjaram Mahipal ; Amoli, Vipin ; Sinha, Anil Kumar ; Mondal, John</creatorcontrib><description>A novel MnFe
O
-porous organic polymer (POP) nanocomposite was synthesized by a facile hydrothermal method and using the highly cross-linked N-rich benzene-benzylamine POP. The nanocomposite presented highly efficient photocatalytic performance in the hydrogen evolution reaction (HER) from pure water without addition of any sacrificial agent under one AM 1.5 G sunlight illumination. A photocatalytic activity of 6.12 mmol h
g
was achieved in the absence of any noble metal cocatalyst, which is the highest H
production rate reported for nonprecious metal catalysts. The photocatalytic performance of MnFe
O
-POP could be attributed to the intrinsic synergistic effects of manganese ferrite (MnFe
O
) nanoclusters interacting with the nitrogen dopant POP with a unique mesoporous nanoarchitecture and spatially confined growth of MnFe
O
in the interconnected POP network, leading to high visible-light absorption with fast electron transport.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201603419</identifier><identifier>PMID: 27595431</identifier><language>eng</language><publisher>Germany</publisher><ispartof>Chemistry : a European journal, 2016-10, Vol.22 (44), p.15639-15644</ispartof><rights>2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1071-4d4c81d8e6bb4076e9471e6922a467e87b1eac93b279096cf011cbec2ad89ba93</citedby><cites>FETCH-LOGICAL-c1071-4d4c81d8e6bb4076e9471e6922a467e87b1eac93b279096cf011cbec2ad89ba93</cites><orcidid>0000-0001-7813-2108</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27923,27924</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27595431$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dhanalaxmi, Karnekanti</creatorcontrib><creatorcontrib>Yadav, Rajkumar</creatorcontrib><creatorcontrib>Kundu, Sudipta K</creatorcontrib><creatorcontrib>Reddy, Benjaram Mahipal</creatorcontrib><creatorcontrib>Amoli, Vipin</creatorcontrib><creatorcontrib>Sinha, Anil Kumar</creatorcontrib><creatorcontrib>Mondal, John</creatorcontrib><title>MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>A novel MnFe
O
-porous organic polymer (POP) nanocomposite was synthesized by a facile hydrothermal method and using the highly cross-linked N-rich benzene-benzylamine POP. The nanocomposite presented highly efficient photocatalytic performance in the hydrogen evolution reaction (HER) from pure water without addition of any sacrificial agent under one AM 1.5 G sunlight illumination. A photocatalytic activity of 6.12 mmol h
g
was achieved in the absence of any noble metal cocatalyst, which is the highest H
production rate reported for nonprecious metal catalysts. The photocatalytic performance of MnFe
O
-POP could be attributed to the intrinsic synergistic effects of manganese ferrite (MnFe
O
) nanoclusters interacting with the nitrogen dopant POP with a unique mesoporous nanoarchitecture and spatially confined growth of MnFe
O
in the interconnected POP network, leading to high visible-light absorption with fast electron transport.</description><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo9kF1LwzAYhYMobk5vvZT8gc58NWm8G9OpMN1AZZclTd9ukfWDpEX67-2Y7urlwDnn5TwI3VIypYSwe7uDcsoIlYQLqs_QmMaMRlzJ-ByNiRYqkjHXI3QVwjchREvOL9GIqVjHgtMx-nmrFoAZXmGB301VW9-H1uwD3njTNJBjV2GD17Wvu4BXfmsqZwe570vwD3iGHyG4bTX4Zt7uXAu27TzgovZ4Y1rw0Uezd23rqi1e7-q2tmYo74ML1-iiGN7Azd-doK_F0-f8JVqunl_ns2VkKVE0ErmwCc0TkFkmiJIwLKIgNWNGSAWJyigYq3nGlB7G2YJQajOwzOSJzozmEzQ99lpfh-ChSBvvSuP7lJL0QDA9EExPBIfA3THQdFkJ-cn-j4z_AtrzbRo</recordid><startdate>20161024</startdate><enddate>20161024</enddate><creator>Dhanalaxmi, Karnekanti</creator><creator>Yadav, Rajkumar</creator><creator>Kundu, Sudipta K</creator><creator>Reddy, Benjaram Mahipal</creator><creator>Amoli, Vipin</creator><creator>Sinha, Anil Kumar</creator><creator>Mondal, John</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7813-2108</orcidid></search><sort><creationdate>20161024</creationdate><title>MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis</title><author>Dhanalaxmi, Karnekanti ; Yadav, Rajkumar ; Kundu, Sudipta K ; Reddy, Benjaram Mahipal ; Amoli, Vipin ; Sinha, Anil Kumar ; Mondal, John</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1071-4d4c81d8e6bb4076e9471e6922a467e87b1eac93b279096cf011cbec2ad89ba93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dhanalaxmi, Karnekanti</creatorcontrib><creatorcontrib>Yadav, Rajkumar</creatorcontrib><creatorcontrib>Kundu, Sudipta K</creatorcontrib><creatorcontrib>Reddy, Benjaram Mahipal</creatorcontrib><creatorcontrib>Amoli, Vipin</creatorcontrib><creatorcontrib>Sinha, Anil Kumar</creatorcontrib><creatorcontrib>Mondal, John</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dhanalaxmi, Karnekanti</au><au>Yadav, Rajkumar</au><au>Kundu, Sudipta K</au><au>Reddy, Benjaram Mahipal</au><au>Amoli, Vipin</au><au>Sinha, Anil Kumar</au><au>Mondal, John</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis</atitle><jtitle>Chemistry : a European journal</jtitle><addtitle>Chemistry</addtitle><date>2016-10-24</date><risdate>2016</risdate><volume>22</volume><issue>44</issue><spage>15639</spage><epage>15644</epage><pages>15639-15644</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>A novel MnFe
O
-porous organic polymer (POP) nanocomposite was synthesized by a facile hydrothermal method and using the highly cross-linked N-rich benzene-benzylamine POP. The nanocomposite presented highly efficient photocatalytic performance in the hydrogen evolution reaction (HER) from pure water without addition of any sacrificial agent under one AM 1.5 G sunlight illumination. A photocatalytic activity of 6.12 mmol h
g
was achieved in the absence of any noble metal cocatalyst, which is the highest H
production rate reported for nonprecious metal catalysts. The photocatalytic performance of MnFe
O
-POP could be attributed to the intrinsic synergistic effects of manganese ferrite (MnFe
O
) nanoclusters interacting with the nitrogen dopant POP with a unique mesoporous nanoarchitecture and spatially confined growth of MnFe
O
in the interconnected POP network, leading to high visible-light absorption with fast electron transport.</abstract><cop>Germany</cop><pmid>27595431</pmid><doi>10.1002/chem.201603419</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-7813-2108</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2016-10, Vol.22 (44), p.15639-15644 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_chem_201603419 |
| source | Wiley Online Library All Journals |
| title | MnFe 2 O 4 Nanocrystals Wrapped in a Porous Organic Polymer: A Designed Architecture for Water-Splitting Photocatalysis |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T11%3A04%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pubmed_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=MnFe%202%20O%204%20Nanocrystals%20Wrapped%20in%20a%20Porous%20Organic%20Polymer:%20A%20Designed%20Architecture%20for%20Water-Splitting%20Photocatalysis&rft.jtitle=Chemistry%20:%20a%20European%20journal&rft.au=Dhanalaxmi,%20Karnekanti&rft.date=2016-10-24&rft.volume=22&rft.issue=44&rft.spage=15639&rft.epage=15644&rft.pages=15639-15644&rft.issn=0947-6539&rft.eissn=1521-3765&rft_id=info:doi/10.1002/chem.201603419&rft_dat=%3Cpubmed_cross%3E27595431%3C/pubmed_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/27595431&rfr_iscdi=true |