Selective P 4 Activation by a Highly Reduced Cobaltate: Synthesis of Dicobalt Tetraphosphido Complexes

Although the chemistry of transition metal polyphosphide anions has attracted significant attention, there are few reports of studies in which such species have been synthesized directly from white phosphorus. [K(OEt ) {Co(BIAN)(cod)}] (1, BIAN=1,2-bis(2,6-diisopropylphenylimino)acenaphthene, cod=1,...

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Veröffentlicht in:Chemistry : a European journal 2017-05, Vol.23 (25), p.6094-6102
Hauptverfasser: Pelties, Stefan, Maier, Thomas, Herrmann, Dirk, de Bruin, Bas, Rebreyend, Christophe, Gärtner, Stefanie, Shenderovich, Ilya G, Wolf, Robert
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Sprache:eng
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