Unusual Chemoselective Rh II ‐Catalysed Transformations of α‐Diazocarbonyl Piperidine Cores

The reactivity of various α‐diazocarbonyl piperidine scaffolds, characterised by an increased molecular complexity, was tested with various Rh II catalysts. The structure of the starting reagent is of relevance to the synthetic results. An unexpected dimerisation took place, starting from the simple...

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Veröffentlicht in:Chemistry : a European journal 2015-01, Vol.21 (4), p.1692-1703
Hauptverfasser: Bonetti, Andrea, Beccalli, Egle, Caselli, Alessandro, Clerici, Francesca, Pellegrino, Sara, Gelmi, Maria Luisa
Format: Artikel
Sprache:eng
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