Double C arom H Activation Associated with Etheral Oxygen Insertion to Phenazine Architecture in Oxidisable Ruthenium(III) Complexes: A Mechanistic Insight
Three examples of unusual double aromatic CH bond activation associated with insertion of etheral oxygen atom to phenazine architecture in Ru III complexes are reported. The chemical transformations have led to the formation of new Ru IV complexes with angular pentacyclo heterocyclic ligands. A mec...
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| Veröffentlicht in: | Chemistry : a European journal 2014-03, Vol.20 (10), p.2712-2717 |
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| container_end_page | 2717 |
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| container_issue | 10 |
| container_start_page | 2712 |
| container_title | Chemistry : a European journal |
| container_volume | 20 |
| creator | Roy, Suman K Samanta, Subhas Chowdhury, Nabanita Saha Mondal, Tapan K. Goswami, Sreebrata |
| description | Three examples of unusual double aromatic CH bond activation associated with insertion of etheral oxygen atom to phenazine architecture in Ru
III
complexes are reported. The chemical transformations have led to the formation of new Ru
IV
complexes with angular pentacyclo heterocyclic ligands. A mechanistic investigation indicates that the overall process is a combination of successive steps involving air (O
2
) and H
2
O. |
| doi_str_mv | 10.1002/chem.201303932 |
| format | Article |
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III
complexes are reported. The chemical transformations have led to the formation of new Ru
IV
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2
) and H
2
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III
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2
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| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2014-03, Vol.20 (10), p.2712-2717 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_chem_201303932 |
| source | Wiley Online Library All Journals |
| title | Double C arom H Activation Associated with Etheral Oxygen Insertion to Phenazine Architecture in Oxidisable Ruthenium(III) Complexes: A Mechanistic Insight |
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