Factors That Regulate the Conformation of m ‐Benziporphodimethene Complexes: Agostic Metal–Arene Interaction, Hydrogen Bonding, and η 2 ,π Coordination

Group 12 and silver(I) tetramethyl‐ m ‐benziporphodimethene (TMBPDM) complexes with phenyl, methylbenzoate, or nitrophenyl groups as meso substituents were synthesized and fully characterized. The dimeric silver(I) complex displays an unusual η 2 ,π coordination from the β‐pyrrolic CC bond to the s...

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Veröffentlicht in:	Chemistry : a European journal 2011-09, Vol.17 (40), p.11332-11343
Hauptverfasser:	Chang, Gao‐Fong, Wang, Chun‐Hung, Lu, Hung‐Chieh, Kan, Lou‐Sing, Chao, Ito, Chen, Wei Hao, Kumar, Anil, Lo, Liyang, dela Rosa, Mira Anne C., Hung, Chen‐Hsiung
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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