Chirality in the Absence of Rigid Stereogenic Elements: The Absolute Configuration of Residual Enantiomers of C 3 ‐Symmetric Propellers
Two new tris(aryl)phosphane oxides existing as configurationally stable residual enantiomers have been synthesised and their racemates resolved by semipreparative HPLC on a chiral stationary phase (CSP HPLC). One of them, recognised as a conglomerate, could be resolved by fractional crystallisation...
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Veröffentlicht in: | Chemistry : a European journal 2009-01, Vol.15 (1), p.86-93 |
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Format: | Artikel |
Sprache: | eng |
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