Chirality in the Absence of Rigid Stereogenic Elements: The Absolute Configuration of Residual Enantiomers of C 3 ‐Symmetric Propellers

Two new tris(aryl)phosphane oxides existing as configurationally stable residual enantiomers have been synthesised and their racemates resolved by semipreparative HPLC on a chiral stationary phase (CSP HPLC). One of them, recognised as a conglomerate, could be resolved by fractional crystallisation...

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Veröffentlicht in:Chemistry : a European journal 2009-01, Vol.15 (1), p.86-93
Hauptverfasser: Benincori, Tiziana, Marchesi, Andrea, Mussini, Patrizia Romana, Pilati, Tullio, Ponti, Alessandro, Rizzo, Simona, Sannicolò, Francesco
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Sprache:eng
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