Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of the Semiconducting Cluster Chain Polymer {[PPh4]2[Te2Ru4(CO)10Cu4Br2Cl2]⋅THF}

A new series of Te–Ru–Cu carbonyl complexes was prepared by the reaction of K2TeO3 with [Ru3(CO)12] in MeOH followed by treatment with PPh4X (X=Br, Cl) and [Cu(MeCN)4]BF4 or CuX (X=Br, Cl) in MeCN. When the reaction mixture of K2TeO3 and [Ru3(CO)12] was first treated with PPh4X followed by the addit...

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Veröffentlicht in:	Chemistry : a European journal 2007-08, Vol.13 (23), p.6605-6616
Hauptverfasser:	Shieh, Minghuey, Hsu, Miao-Hsing, Sheu, Wen-Shyan, Jang, Li-Fing, Lin, Shu-Fen, Chu, Yen-Yi, Miu, Chia-Yeh, Lai, Yun-Wen, Liu, Hsiang-Lin, Her, Jim Long
Format:	Artikel
Sprache:	eng
Schlagworte:	carbonyl ligands cluster compounds copper ruthenium tellurium
Online-Zugang:	Volltext
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