Acceptorless Dehydrogenation of Alcohols Catalyzed by Cu I N ‐Heterocycle Thiolate Complexes
Cu I N ‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of...
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| Veröffentlicht in: | ChemCatChem 2017-03, Vol.9 (6), p.1113-1118 |
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| container_issue | 6 |
| container_start_page | 1113 |
| container_title | ChemCatChem |
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| creator | Tan, Da‐Wei Li, Hong‐Xi Zhang, Meng‐Juan Yao, Jian‐Lin Lang, Jian‐Ping |
| description | Cu
I
N
‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of H
2
. This simple catalytic system is involved in the synthesis of imines through the one‐pot reaction of alcohols and amines. |
| doi_str_mv | 10.1002/cctc.201601459 |
| format | Article |
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I
N
‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of H
2
. This simple catalytic system is involved in the synthesis of imines through the one‐pot reaction of alcohols and amines.</description><identifier>ISSN: 1867-3880</identifier><identifier>EISSN: 1867-3899</identifier><identifier>DOI: 10.1002/cctc.201601459</identifier><language>eng</language><ispartof>ChemCatChem, 2017-03, Vol.9 (6), p.1113-1118</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c169t-7df43a0e5579ce51acd37af6cb7f7e76f418fabad4697474e2a088a908eddf03</citedby><cites>FETCH-LOGICAL-c169t-7df43a0e5579ce51acd37af6cb7f7e76f418fabad4697474e2a088a908eddf03</cites><orcidid>0000-0003-2942-7385</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Tan, Da‐Wei</creatorcontrib><creatorcontrib>Li, Hong‐Xi</creatorcontrib><creatorcontrib>Zhang, Meng‐Juan</creatorcontrib><creatorcontrib>Yao, Jian‐Lin</creatorcontrib><creatorcontrib>Lang, Jian‐Ping</creatorcontrib><title>Acceptorless Dehydrogenation of Alcohols Catalyzed by Cu I N ‐Heterocycle Thiolate Complexes</title><title>ChemCatChem</title><description>Cu
I
N
‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of H
2
. This simple catalytic system is involved in the synthesis of imines through the one‐pot reaction of alcohols and amines.</description><issn>1867-3880</issn><issn>1867-3899</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNo90DtOAzEUhWELgUQItNTewAQ7M-NHGQ2PRIqgSc3o5vqaBDlxZBuJoWIJrJGVoAhEdf7qFB9j11JMpBDTG8SCk6mQSsimtSdsJI3SVW2sPf1vI87ZRc6vQihb63bEnmeIdCgxBcqZ39JmcCm-0B7KNu559HwWMG5iyLyDAmH4IMfXA-_e-II_8u_PrzkVShEHDMRXm20MUIh3cXcI9E75kp15CJmu_nbMVvd3q25eLZ8eFt1sWaFUtlTa-aYGQW2rLVIrAV2twStca69JK99I42ENrlFWN7qhKQhjwApDznlRj9nk9xZTzDmR7w9pu4M09FL0R5z-iNP_49Q_h2Na8w</recordid><startdate>20170320</startdate><enddate>20170320</enddate><creator>Tan, Da‐Wei</creator><creator>Li, Hong‐Xi</creator><creator>Zhang, Meng‐Juan</creator><creator>Yao, Jian‐Lin</creator><creator>Lang, Jian‐Ping</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid></search><sort><creationdate>20170320</creationdate><title>Acceptorless Dehydrogenation of Alcohols Catalyzed by Cu I N ‐Heterocycle Thiolate Complexes</title><author>Tan, Da‐Wei ; Li, Hong‐Xi ; Zhang, Meng‐Juan ; Yao, Jian‐Lin ; Lang, Jian‐Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c169t-7df43a0e5579ce51acd37af6cb7f7e76f418fabad4697474e2a088a908eddf03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tan, Da‐Wei</creatorcontrib><creatorcontrib>Li, Hong‐Xi</creatorcontrib><creatorcontrib>Zhang, Meng‐Juan</creatorcontrib><creatorcontrib>Yao, Jian‐Lin</creatorcontrib><creatorcontrib>Lang, Jian‐Ping</creatorcontrib><collection>CrossRef</collection><jtitle>ChemCatChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tan, Da‐Wei</au><au>Li, Hong‐Xi</au><au>Zhang, Meng‐Juan</au><au>Yao, Jian‐Lin</au><au>Lang, Jian‐Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acceptorless Dehydrogenation of Alcohols Catalyzed by Cu I N ‐Heterocycle Thiolate Complexes</atitle><jtitle>ChemCatChem</jtitle><date>2017-03-20</date><risdate>2017</risdate><volume>9</volume><issue>6</issue><spage>1113</spage><epage>1118</epage><pages>1113-1118</pages><issn>1867-3880</issn><eissn>1867-3899</eissn><abstract>Cu
I
N
‐heterocycle thiolate clusters efficiently catalyze the acceptorless dehydrogenation of alcohols at 70 °C. A variety of secondary/primary benzylic, allylic, and aliphatic alcohols are dehydrogenated to the corresponding ketones and aldehydes in high yields of isolated product upon release of H
2
. This simple catalytic system is involved in the synthesis of imines through the one‐pot reaction of alcohols and amines.</abstract><doi>10.1002/cctc.201601459</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-2942-7385</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1867-3880 |
| ispartof | ChemCatChem, 2017-03, Vol.9 (6), p.1113-1118 |
| issn | 1867-3880 1867-3899 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_cctc_201601459 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Acceptorless Dehydrogenation of Alcohols Catalyzed by Cu I N ‐Heterocycle Thiolate Complexes |
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