Enzyme-Catalyzed Carbonyl Olefination by the E. coli Protein YfeX in the Absence of Phosphines

The Wittig‐type carbonyl olefination reaction has no biocatalytic equivalent. To build complex molecular scaffolds, however, C−C bond‐forming reactions are pivotal for biobased economy and synthetic biology. The heme‐containing E. coli protein YfeX was found to catalyze carbonyl olefination by react...

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Veröffentlicht in:	ChemCatChem 2016-05, Vol.8 (9), p.1636-1640
Hauptverfasser:	Weissenborn, Martin J., Löw, Sebastian A., Borlinghaus, Niels, Kuhn, Miriam, Kummer, Stefanie, Rami, Fabian, Plietker, Bernd, Hauer, Bernhard
Format:	Artikel
Sprache:	eng
Schlagworte:	biocatalysis C−C bond formation enzyme catalysis olefination Wittig reactions
Online-Zugang:	Volltext
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