Organophosphorus Compounds, 118. Reactions of 1‐Chloro‐1 H ‐phosphirenes with Nucleophiles
The halogen atoms in the 1‐chloro‐1 H ‐phosphirenes, 5a – c , are easily substituted on reaction with organolithium and Grignard reagents, 14a – p , with formation of the corresponding O‐, N‐, C‐, Si‐, and Ge‐substituted 1 H ‐phosphirenes, 15a – t . C1/H exchange reactions also occur on reaction wit...
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| Veröffentlicht in: | Chemische Berichte 1997-06, Vol.130 (6), p.711-723 |
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| container_title | Chemische Berichte |
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| creator | Heydt, Heinrich Ehle, Michael Haber, Steffen Hoffmann, Jürgen Wagner, Oliver Göller, Andreas Clark, Timothy Regitz, Manfred |
| description | The halogen atoms in the 1‐chloro‐1
H
‐phosphirenes,
5a
–
c
, are easily substituted on reaction with organolithium and Grignard reagents,
14a
–
p
, with formation of the corresponding O‐, N‐, C‐, Si‐, and Ge‐substituted 1
H
‐phosphirenes,
15a
–
t
. C1/H exchange reactions also occur on reaction with lithium metal hydrides (
5a
→
17
). Furthermore, substitution reactions are also realized with the alkali metal borates,
18a
–
g
(→
19a
–
g
); the same is true for reactions with trimethylsilyl cyanide and azide (→
22a
–
d
). Some of the substitution products have been characterized in the form of their metal complexes,
16, 23, 24
, and
25
. |
| doi_str_mv | 10.1002/cber.19971300607 |
| format | Article |
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H
‐phosphirenes,
5a
–
c
, are easily substituted on reaction with organolithium and Grignard reagents,
14a
–
p
, with formation of the corresponding O‐, N‐, C‐, Si‐, and Ge‐substituted 1
H
‐phosphirenes,
15a
–
t
. C1/H exchange reactions also occur on reaction with lithium metal hydrides (
5a
→
17
). Furthermore, substitution reactions are also realized with the alkali metal borates,
18a
–
g
(→
19a
–
g
); the same is true for reactions with trimethylsilyl cyanide and azide (→
22a
–
d
). Some of the substitution products have been characterized in the form of their metal complexes,
16, 23, 24
, and
25
.</description><identifier>ISSN: 0009-2940</identifier><identifier>DOI: 10.1002/cber.19971300607</identifier><language>eng</language><ispartof>Chemische Berichte, 1997-06, Vol.130 (6), p.711-723</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c887-ebe963f9239e20dac5f36bfbca9dc19bbacd8773d730b14a638c23dab079a3cc3</citedby><cites>FETCH-LOGICAL-c887-ebe963f9239e20dac5f36bfbca9dc19bbacd8773d730b14a638c23dab079a3cc3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27922,27923</link.rule.ids></links><search><creatorcontrib>Heydt, Heinrich</creatorcontrib><creatorcontrib>Ehle, Michael</creatorcontrib><creatorcontrib>Haber, Steffen</creatorcontrib><creatorcontrib>Hoffmann, Jürgen</creatorcontrib><creatorcontrib>Wagner, Oliver</creatorcontrib><creatorcontrib>Göller, Andreas</creatorcontrib><creatorcontrib>Clark, Timothy</creatorcontrib><creatorcontrib>Regitz, Manfred</creatorcontrib><title>Organophosphorus Compounds, 118. Reactions of 1‐Chloro‐1 H ‐phosphirenes with Nucleophiles</title><title>Chemische Berichte</title><description>The halogen atoms in the 1‐chloro‐1
H
‐phosphirenes,
5a
–
c
, are easily substituted on reaction with organolithium and Grignard reagents,
14a
–
p
, with formation of the corresponding O‐, N‐, C‐, Si‐, and Ge‐substituted 1
H
‐phosphirenes,
15a
–
t
. C1/H exchange reactions also occur on reaction with lithium metal hydrides (
5a
→
17
). Furthermore, substitution reactions are also realized with the alkali metal borates,
18a
–
g
(→
19a
–
g
); the same is true for reactions with trimethylsilyl cyanide and azide (→
22a
–
d
). Some of the substitution products have been characterized in the form of their metal complexes,
16, 23, 24
, and
25
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H
‐phosphirenes,
5a
–
c
, are easily substituted on reaction with organolithium and Grignard reagents,
14a
–
p
, with formation of the corresponding O‐, N‐, C‐, Si‐, and Ge‐substituted 1
H
‐phosphirenes,
15a
–
t
. C1/H exchange reactions also occur on reaction with lithium metal hydrides (
5a
→
17
). Furthermore, substitution reactions are also realized with the alkali metal borates,
18a
–
g
(→
19a
–
g
); the same is true for reactions with trimethylsilyl cyanide and azide (→
22a
–
d
). Some of the substitution products have been characterized in the form of their metal complexes,
16, 23, 24
, and
25
.</abstract><doi>10.1002/cber.19971300607</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Chemische Berichte, 1997-06, Vol.130 (6), p.711-723 |
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| language | eng |
| recordid | cdi_crossref_primary_10_1002_cber_19971300607 |
| source | Wiley Online Library All Journals |
| title | Organophosphorus Compounds, 118. Reactions of 1‐Chloro‐1 H ‐phosphirenes with Nucleophiles |
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