Mixed Bent Sandwich Titanium Complexes with the [2-(Diisopropylamino)ethyl]cyclopentadienyl Ligand - Catalysts for the Polymerization of Ethylene and the Dehydrocoupling of Phenylsilane

Mixed bent sandwich titanium (IV) complexes containing the donor‐substituted [2‐(diisopropylamino)ethyl]cyclopentadienyl (C5H4CH2CH2NiPr2  CpN) ligand are described. The highly moisture‐sensitive metallocene dichloride (C5H4CH2CH2NNiPr2)(C5H4SiMe3)TiCl2 (1) was synthesized by reaction of CpNLi with...

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Veröffentlicht in:	Chemische Berichte 1996-12, Vol.129 (12), p.1509-1515
Hauptverfasser:	Jutzi, Peter, Redeker, Thomas, Neumann, Beate, Stammler, Hans-Georg
Format:	Artikel
Sprache:	eng
Schlagworte:	Dehydrocoupling of phenylsilane Ethylene polymerization N-Functionalized cyclopentadienyl ligands Substituted metallocene complexes
Online-Zugang:	Volltext
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